The Structure and Reactivity of Phosphorus Pentachloride

Data are presented on the reactions of phosphorus pentachloride with compounds containing oxa- and oxy-groups (ethers, acetals, oxetans, tetrahydrofuran, 1,3-dioxans, dioxolans, dihydropyrans, and alcohols). The structure of phosphorus pentachloride in various solvents and its influence on the course of reactions are considered. The mechanisms proposed for the reactions under discussion are analysed.
The bibliography includes 119 references.