Abstract:
Data are presented on the reactions of phosphorus pentachloride with compounds containing oxa- and oxy-groups (ethers, acetals, oxetans, tetrahydrofuran, 1,3-dioxans, dioxolans, dihydropyrans, and alcohols). The structure of phosphorus pentachloride in various solvents and its influence on the course of reactions are considered. The mechanisms proposed for the reactions under discussion are analysed. The bibliography includes 119 references.
Bibliographic databases:
Document Type:
Article
UDC:
547.241.547.313
Language: English
Original paper language: Russian
Citation:
S. V. Fridland, B. D. Chernokal'skii, “The Structure and Reactivity of Phosphorus Pentachloride”, Usp. Khim., 47:8 (1978), 1397–1413; Russian Chem. Reviews, 47:8 (1978), 742–750
Linking options:
https://www.mathnet.ru/eng/rcr3073
https://doi.org/10.1070/RC1978v047n08ABEH002257
https://www.mathnet.ru/eng/rcr/v47/i8/p1397
This publication is cited in the following 9 articles:
V. F. Mironov, G. G. Sergeenko, I. Bauer, W. -D. Habicher, Russ J Org Chem, 42:10 (2006), 1453
L. I. Markova, N. G. Korobochkina, V. G. Kharchenko, Chem Heterocycl Compd, 35:6 (1999), 746
Studies in Inorganic Chemistry, 20, Phosphorus - An Outline of its Chemistry, Biochemistry and Uses, 1995, 65
Alan B. Brown, Chris W. Chronister, Diana M. Watkins, Richard J. Mazzaccaro, Scott R. Rajski, Martha G. Fountain, Scott E. McKay, Tracy L. Gibson, Synthetic Communications, 25:4 (1995), 485
Studies in Inorganic Chemistry, 10, Phosphorus - An Outline of its Chemistry, Biochemistry and Technology, 1990, 55
Paul F. Hudrlik, Ashok K. Kulkarni, Tetrahedron, 41:7 (1985), 1179
Studies in Inorganic Chemistry, 6, Phosphorus - An Outline of its Chemistry, Biochemistry and Technology, 1985, 45
Studies in Inorganic Chemistry, 2, Phosphorus - An Outline of its Chemistry, Biochemistry and Technology, 1980, 33
S. V. FRIDLAND, B. D. CHERNOKAL'SKII, Chemischer Informationsdienst, 9:50 (1978)
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