|
The Hydroperoxy-radical ($\mathrm{H}\dot{\mathrm{O}}_2$) in V. V. Voevodskii's Research and at the Present Time. Results and Problems
V. L. Tal'roze, A. I. Poroikova Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
Abstract:
The role of $\mathrm{H}\dot{\mathrm{O}}_2$ radicals in the kinetics of the gas-phase oxidation of hydrogen-containing substances is considered. It is shown that at a high concentration of active centres, for example, when the latter are generated under the influence of a fairly powerful radiation source, non-linear reactions of $\mathrm{H}\dot{\mathrm{O}}_2$ radicals, i.e. their interaction with one another and with other active species, become important. These processes play an important role in the following kinetic systems considered: at the second limit in mixtures of hydrogen with oxygen under the conditions of artificial chain initiation; in the region of Earth's ozone layer; in lasers based on the reactions between $\mathrm{H}_2$ and $\mathrm{F}_2$.
The bibliography includes 44 references.
Citation:
V. L. Tal'roze, A. I. Poroikova, “The Hydroperoxy-radical ($\mathrm{H}\dot{\mathrm{O}}_2$) in V. V. Voevodskii's Research and at the Present Time. Results and Problems”, Usp. Khim., 47:6 (1978), 955–966; Russian Chem. Reviews, 47:6 (1978), 496–502
Linking options:
https://www.mathnet.ru/eng/rcr3059https://doi.org/10.1070/RC1978v047n06ABEH002234 https://www.mathnet.ru/eng/rcr/v47/i6/p955
|
Statistics & downloads: |
Abstract page: | 79 |
|