Abstract:
Experimental and calculated data on the kinetics of ′blue' flame observed in the gas-phase oxidation and combustion of hydrocarbons and their derivatives are considered. It is shown that blue flames arise due to the decomposition of hydrogen peroxide that forms in the oxidation of hydrocarbons. They manifest themselves by light emission, are identified by partial heat release (the appearance of a step in the time dependences of temperature and pressure observed in closed-vessel experiments) and propagate as conventional hot flames.
Received: 07.03.2007
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Document Type:
Article
Language: English
Original paper language: Russian
Citation:
V. Ya. Basevich, S. M. Frolov, “Kinetics of ′blue' flames in the gas-phase oxidation and combustion of hydrocarbons and their derivatives”, Usp. Khim., 76:9 (2007), 927–944; Russian Chem. Reviews, 76:9 (2007), 867–884
Linking options:
https://www.mathnet.ru/eng/rcr305
https://doi.org/10.1070/RC2007v076n09ABEH003703
https://www.mathnet.ru/eng/rcr/v76/i9/p927
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