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This article is cited in 37 scientific papers (total in 37 papers)
Advances in the development of new catalysts for ethylene and α-olefin polymerisation
S. S. Ivanchev St. Petersburg Department of G.K. Boreskov Institute of Catalysis SB RAS
Abstract:
The role of catalyst systems in the perfection of polymerisation processes and the improvement of the performance characteristics of polyethylene and other polyolefins is considered. The scope of application of post-metallocene catalysts based on transition metal α-diimine, bis(imino)pyridine and phenoxy imine complexes designed in the last decade is analysed. The structures of complexes depending on the type of ligands are described systematically. The development of research into these catalyst systems is discussed, the optimal structures as regards the activity and selectivity are mentioned, and the mechanism of their action and the prospects for industrial use are demonstrated.
Received: 22.01.2007
Citation:
S. S. Ivanchev, “Advances in the development of new catalysts for ethylene and α-olefin polymerisation”, Usp. Khim., 76:7 (2007), 669–690; Russian Chem. Reviews, 76:7 (2007), 617–637
Linking options:
https://www.mathnet.ru/eng/rcr292https://doi.org/10.1070/RC2007v076n07ABEH003694 https://www.mathnet.ru/eng/rcr/v76/i7/p669
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