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This article is cited in 16 scientific papers (total in 16 papers)
Four- and Five-membered Cyclic Disulphides
T. P. Vasil'eva, M. G. Lin'kova, O. V. Kil'disheva A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow
Abstract:
The principal methods for synthesising 1,2-dithiolans are surveyed, together with their advantages and disadvantages. Information is given on the geometry of the 1,2-dithiolan ring. The polarography, photolysis, and spectra of 1,2-dithiolans are discussed, and results are given for their polymerisation, reduction, oxidation, and chlorolysis, as well as the removal of a sulphur atom. Data are presented on the biological importance and application of 1,2-dithiolans. The major part of the review is devoted to the chemistry of unsaturated five-membered cyclic disulphides – the 3-thiones, 3-ones, 3-imines, and 3-ylidenes of 1,2-dithiolens – with methods of preparation and both chemical and physical properties. A detailed examination is made of their reactions with electrophilic and nucleophilic reagents, as well as condensations. Fields of practical application of 1,2-dithiolens are surveyed. The review concludes with 233 references.
Citation:
T. P. Vasil'eva, M. G. Lin'kova, O. V. Kil'disheva, “Four- and Five-membered Cyclic Disulphides”, Usp. Khim., 45:7 (1976), 1269–1315; Russian Chem. Reviews, 45:7 (1976), 639–659
Linking options:
https://www.mathnet.ru/eng/rcr2904https://doi.org/10.1070/RC1976v045n07ABEH002700 https://www.mathnet.ru/eng/rcr/v45/i7/p1269
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