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This article is cited in 71 scientific papers (total in 71 papers)
Complex phosphates, formed by metal cations in oxidation states I and IV
V. I. Pet'kov N. I. Lobachevski State University of Nizhni Novgorod, Department of Chemistry
Abstract:
Data on the synthesis, structure and physicochemical characteristics of phosphates formed by MI and EIV cations, in particular, double and more complex phosphates in which MI has been partially replaced by H+ or (M')I and PO43– has been partially replaced by TO4n– (T=Si, As, B, Mo) are generalized and described systematically. The key factors responsible for the formation of a particular type of structure are analyzed. The possibilities are considered for preparing structures of a desired type and symmetry and for fine tuning of properties of obtained crystals by varying the cationic and anionic components of the phosphate with retention of stable structural fragments of the crystal ensemble and by selecting an appropriate method of synthesis. The ways of practical application of complex phosphates taking into account their structural features are demonstrated. Bibliography — 395 references.
Received: 15.05.2011
Citation:
V. I. Pet'kov, “Complex phosphates, formed by metal cations in oxidation states I and IV”, Usp. Khim., 81:7 (2012), 606–637; Russian Chem. Reviews, 81:7 (2012), 606–637
Linking options:
https://www.mathnet.ru/eng/rcr29https://doi.org/10.1070/RC2012v081n07ABEH004243 https://www.mathnet.ru/eng/rcr/v81/i7/p606
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