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This article is cited in 38 scientific papers (total in 38 papers)
Modern trends in the development of surface science as applied to catalysis. The elucidation of the structure–activity relationships in heterogeneous catalysts
V. I. Bukhtiyarov Boreskov Institute of Catalysis SB RAS, Novosibirsk
Abstract:
A fundamental approach to the development of heterogeneous catalysts consisting of the study of the structure–activity relationships using surface science methods and techniques is proposed. According to this approach, a study should start with an investigation into well-ordered single crystals under ultrahigh vacuum conditions and then move along the way of both increasing the gas phase pressure (to address the ′pressure gap' problem) and complicating the samples under study from single crystals to supported clusters (to address the ′material gap' problem). The case studies cited in the review prove the efficacy of the proposed approach to investigations into the reactivity of active component particles for the subsequent molecular design of catalysts with improved performance (activity, selectivity and stability) and demonstrate that it conforms with the modern trends in the development of surface science as applied to heterogeneous catalysis.
Received: 17.04.2007
Citation:
V. I. Bukhtiyarov, “Modern trends in the development of surface science as applied to catalysis. The elucidation of the structure–activity relationships in heterogeneous catalysts”, Usp. Khim., 76:6 (2007), 596–627; Russian Chem. Reviews, 76:6 (2007), 553–581
Linking options:
https://www.mathnet.ru/eng/rcr289https://doi.org/10.1070/RC2007v076n06ABEH003721 https://www.mathnet.ru/eng/rcr/v76/i6/p596
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