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This article is cited in 43 scientific papers (total in 43 papers)
Reaction Mechanisms of the Direct Epoxidation of Alkenes in the Liquid Phase
D. I. Metelitsa Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
Abstract:
Reaction mechanisms for the liquid-phase epoxidation of alkenes are reviewed critically: the classical Prilezhaev reaction, catalytic epoxidation with participation of hydrogen peroxide and of organic hydroperoxides, reactions for the production of alkene oxides in the oxidation of unsaturated hydrocarbons, reaction of a combined oxidation of alkenes with aldehydes. The mechanism and prospects of the catalysed oxidation with oxygen of alkenes to epoxides are discussed in detail. 150 references.
Citation:
D. I. Metelitsa, “Reaction Mechanisms of the Direct Epoxidation of Alkenes in the Liquid Phase”, Usp. Khim., 41:10 (1972), 1737–1765; Russian Chem. Reviews, 41:10 (1972), 807–821
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https://www.mathnet.ru/eng/rcr2570https://doi.org/10.1070/RC1972v041n10ABEH002095 https://www.mathnet.ru/eng/rcr/v41/i10/p1737
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