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This article is cited in 9 scientific papers (total in 9 papers)
Conversions of Chlorine-containing Aliphatic Compounds in the Presence of Coordination-unsaturated Metals
A. E. Kulikova, E. N. Zil'berman
Abstract:
Conversions of aliphatic chlorine-containing compounds (chloroalkenes, chloroalkanes, and derivatives of chloro-substituted carboxylic acids) occur under the action of aprotic acids. Chloroethylenes are polymerised by a cationic mechanism with the formation of oligomeric and polymeric products. The principal reaction of chloroalkanes and chlorocycloalkanes in the presence of salts of coordination-unsaturated metals is dehydrochlorination, which proceeds either intramolecularly or intermolecularly with the formation of polymers with conjugated double bonds. For polychloro-containing compounds, in addition to the dehydrochlorinations, elimination of chlorine occurs. Perchloroalkanes (from C3 and higher) in the presence of aprotic acids also undergo degradation with breaking of the carbon–carbon bond. There is a bibliography of 353 references.
Citation:
A. E. Kulikova, E. N. Zil'berman, “Conversions of Chlorine-containing Aliphatic Compounds in the Presence of Coordination-unsaturated Metals”, Usp. Khim., 40:3 (1971), 462–490; Russian Chem. Reviews, 40:3 (1971), 256–271
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https://www.mathnet.ru/eng/rcr2435https://doi.org/10.1070/RC1971v040n03ABEH001917 https://www.mathnet.ru/eng/rcr/v40/i3/p462
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