Abstract:
Quantitative data on the photochemical activity of aromatic azides and on the mechanism and kinetics of azido group photodissociation are analysed and described systematically for the first time. The results of quantum chemical calculations of the azide structure in the ground and lower electronically excited states and the potential energy surfaces along the reaction coordinate of the N–N2 bond dissociation are considered.
Received: 20.03.2008
Bibliographic databases:
Document Type:
Article
Language: English
Original paper language: Russian
Citation:
M. F. Budyka, “Photodissociation of aromatic azides”, Usp. Khim., 77:8 (2008), 757–772; Russian Chem. Reviews, 77:8 (2008), 709–723
Linking options:
https://www.mathnet.ru/eng/rcr240
https://doi.org/10.1070/RC2008v077n08ABEH003793
https://www.mathnet.ru/eng/rcr/v77/i8/p757
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