Abstract:
The review describes the modern concepts concerning the electronic fine structure of aliphatic diazo-compounds based on experimental data (from infrared, ultraviolet, and PMR spectroscopy) and also quantum-mechanical calculations by the LCAO-MO method. These concepts explain many chemical properties of diazoalkanes and sometimes make it possible to predict them. Apart from "classical" aliphatic diazo-compounds, the structures and properties of the isomers – linear (N-isocyanamine) and cyclic (diazirines) – are considered. The bibliography comprises 99 references.
Bibliographic databases:
Document Type:
Article
UDC:
547.02:547.235:547.717:543.422
Language: English
Original paper language: Russian
Citation:
O. P. Studzinskii, I. K. Korobitsyna, “The Structure of Aliphatic Diazo-compounds and Their Isomers”, Usp. Khim., 39:10 (1970), 1754–1772; Russian Chem. Reviews, 39:10 (1970), 834–843
Linking options:
https://www.mathnet.ru/eng/rcr2395
https://doi.org/10.1070/RC1970v039n10ABEH002046
https://www.mathnet.ru/eng/rcr/v39/i10/p1754
This publication is cited in the following 9 articles:
Rodina L.L. Baranovskii V.I. Galkina O.S. Nikolaev V.A. Tonogina N.L. Povolotskiy A.V., J. Org. Chem., 82:21 (2017), 11399–11405
Wei Lu, Yongxin Li, Rakesh Ganguly, Rei Kinjo, Angew Chem Int Ed, 56:33 (2017), 9829
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