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This article is cited in 19 scientific papers (total in 19 papers)
Reactivity of Trivalent Phosphorus Derivatives
B. E. Ivanov, V. F. Zheltukhin A. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Branch of the USSR Academy of Sciences
Abstract:
The review deals with the most important features of phosphorus(III) derivatives, which determine their chemical properties. These are the biphilicity of the phosphorus atoms due to the presence of a free electron pair and unfilled d orbitals and the ambidentate properties of phosphorus(III) derivatives determined by the specific contribution of both nucleophilic elements (O, N, S) and elements with vacant d orbitals (Si, Sn) directly linked to the phosphorus atom. Certain limits and characteristics of this contribution have been elucidated and the mechanism of the relevant reactions has been discussed. The last section deals with the specificity of the behaviour of phosphorus(III) compounds with a phosphorus–halogen bond. The significant role of the d orbitals of the phosphorus atom in its chemical reactivity is discussed. The bibliography comprises 197 references.
Citation:
B. E. Ivanov, V. F. Zheltukhin, “Reactivity of Trivalent Phosphorus Derivatives”, Usp. Khim., 39:5 (1970), 773–802; Russian Chem. Reviews, 39:5 (1970), 358–372
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https://www.mathnet.ru/eng/rcr2355https://doi.org/10.1070/RC1970v039n05ABEH001993 https://www.mathnet.ru/eng/rcr/v39/i5/p773
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