Russian Chemical Reviews
RUS  ENG    JOURNALS   PEOPLE   ORGANISATIONS   CONFERENCES   SEMINARS   VIDEO LIBRARY   PACKAGE AMSBIB  
General information
Latest issue
Archive
Impact factor
Guidelines for authors

Search papers
Search references

RSS
Latest issue
Current issues
Archive issues
What is RSS



Usp. Khim.:
Year:
Volume:
Issue:
Page:
Find






Personal entry:
Login:
Password:
Save password
Enter
Forgotten password?
Register


Russian Chemical Reviews, 1969, Volume 38, Issue 10, Pages 795–811
DOI: https://doi.org/10.1070/RC1969v038n10ABEH001839
(Mi rcr2300)
 

This article is cited in 92 scientific papers (total in 92 papers)

The Application of the Hammett Equation with the Constants σph in the Chemistry of Organophosphorus Compounds

T. A. Mastryukova, M. I. Kabachnik

A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow
English full-text Citations (92)
Abstract: The review deals with the application of the Hammett equation to organophosphorus reactions and equilibria using the constants σph. As far as possible a complete list of the constants σph is given. Analysis of the application of the constants σph shows that linear correlations between the rate and equilibrium constants for organophosphorus reactions are usually obtained when the phosphorus atom is not a reaction centre.
For reactions involving phosphorus directly, linear correlations are achieved with the aid of the inductive (σphI) and resonance (σphR) constants, namely: Σ(σphI+ασphR). A method of calculation of the constants σphI and σphR is described and as far as possible a complete list of these constants is given for various groups attached to the phosphorus atom. It has been demonstrated on 124 reaction series as examples the function Σ(σphI+ασphR) makes it possible to construct a universal system for the σρ analysis of reactions, equilibria, and certain physical constants in the chemistry of organophosphorus compounds on the basis of the equation lgK = lgK0+ρΣ(σphI+ασphR) with high correlation coefficients. The relation between the constants α and ρ on the one hand and the type of reaction and its mechanism on the other is discussed.
The bibliography includes 117 references.
Russian version:
Uspekhi Khimii, 1969, Volume 38, Issue 10, Pages 1751–1782
DOI: https://doi.org/10.1070/RC1969v038n10ABEH001839
Document Type: Article
UDC: 547.241+541.127
Language: English
Original paper language: Russian


Citation: T. A. Mastryukova, M. I. Kabachnik, “The Application of the Hammett Equation with the Constants σph in the Chemistry of Organophosphorus Compounds”, Usp. Khim., 38:10 (1969), 1751–1782; Russian Chem. Reviews, 38:10 (1969), 795–811
Linking options:
  • https://www.mathnet.ru/eng/rcr2300
  • https://doi.org/10.1070/RC1969v038n10ABEH001839
  • https://www.mathnet.ru/eng/rcr/v38/i10/p1751
  • This publication is cited in the following 92 articles:
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
    Успехи химии Russian Chemical Reviews
    Statistics & downloads:
    Abstract page:160
     
      Contact us:
     Terms of Use  Registration to the website  Logotypes © Steklov Mathematical Institute RAS, 2024