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This article is cited in 51 scientific papers (total in 51 papers)
Macromolecular metal carboxylates
G. I. Dzhardimalieva, A. D. Pomogailo Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
Abstract:
Data on the synthesis and physicochemical studies of salts of mono- or dibasic unsaturated carboxylic acids and unsaturated metal oxo-carboxylates are generalised and described systematically. The structures and properties of the COO group in various compounds and characteristic features of the structures of carboxylate complexes are analysed. The main routes and kinetics of polymerisation transformations of unsaturated metal carboxylates are considered. The attention is focused on the effect of the metal ion on the monomer reactivity and the polymer morphology and structure. The possibility of stereochemical control of radical polymerisation of unsaturated metal carboxylates is demonstrated. The electronic, magnetic, optical, absorption and thermal properties of metal (co)polymers and nanocomposites and their main applications are considered.
Received: 27.11.2006
Citation:
G. I. Dzhardimalieva, A. D. Pomogailo, “Macromolecular metal carboxylates”, Usp. Khim., 77:3 (2008), 270–315; Russian Chem. Reviews, 77:3 (2008), 259–301
Linking options:
https://www.mathnet.ru/eng/rcr219https://doi.org/10.1070/RC2008v077n03ABEH003682 https://www.mathnet.ru/eng/rcr/v77/i3/p270
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