Outer-sphere interaction in aqueous solutions of complex compounds

CONTENTS
I. Introduction 455
II. Standardisation of conditions for studying outer-sphere association in aqueous solutions of complex compounds 456
III. Procedure for calculating the outer-sphere association constants for labile complexes 457
IV. The most widely used methods for determining outer-sphere association constants 459
V. Outer-sphere association and the law of mass action 459
VI. Some rules of outer-sphere association 461
VII. Prediction of constants for the association of anionic complexes with alkali metal cations 465
VIII. Comparison of outer-sphere and inner-sphere association constants 465
IX. Complex formation with allowance for associative interaction with the ions of the salt medium 466