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This article is cited in 17 scientific papers (total in 17 papers)
Spectroscopy and structure of free radicals stabilized in cryogenic matrices
E. G. Baskira, E. Ya. Misochkob, O. M. Nefedova a N.D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences
b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
Abstract:
The results of spectroscopic (mainly vibrational IR spectroscopy and EPR spectroscopy) studies of radicals stabilized in solid inert-gas matrices are considered. Attention is focused on a comparison of experimental spectroscopic characteristics of radicals with those simulated by modern quantum chemical computation methods and on the use of these data for the elucidation of molecular and electronic structures of free radicals. The potential of new methods for radical generation in cryogenic matrices and the prospects for their application in spectroscopic studies are discussed. Data from the recent and earlier studies are compared.
Received: 02.11.2007
Citation:
E. G. Baskir, E. Ya. Misochko, O. M. Nefedov, “Spectroscopy and structure of free radicals stabilized in cryogenic matrices”, Usp. Khim., 78:8 (2009), 742–775; Russian Chem. Reviews, 78:8 (2009), 683–715
Linking options:
https://www.mathnet.ru/eng/rcr180https://doi.org/10.1070/RC2009v078n08ABEH003758 https://www.mathnet.ru/eng/rcr/v78/i8/p742
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