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This article is cited in 28 scientific papers (total in 28 papers)
Reactions of nitrogen oxides with polymers
G. B. Pariiskii, I. S. Gaponova, E. Ya. Davydov Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow
Abstract:
The mechanisms of the reactions of nitrogen oxides and different classes of solid polymers are considered. Particular emphasis is given to the analysis of the mechanisms of the formation of stable nitroxyl radicals. Double bonds and amide groups of macromolecules, as well as hydroperoxides and peroxide macroradicals are shown to be involved in the reactions with nitrogen oxides. The application of nitrogen oxides for the preparation of spin-labelled polymers and the use of the ESR imaging technique (ESR tomography) for the investigation of the structure of the reaction front during nitration of solid polymers are considered. The bibliography includes 111 references.
Received: 11.07.2000
Citation:
G. B. Pariiskii, I. S. Gaponova, E. Ya. Davydov, “Reactions of nitrogen oxides with polymers”, Usp. Khim., 69:11 (2000), 1071–1086; Russian Chem. Reviews, 69:11 (2000), 985–999
Linking options:
https://www.mathnet.ru/eng/rcr1553https://doi.org/10.1070/RC2000v069n11ABEH000611 https://www.mathnet.ru/eng/rcr/v69/i11/p1071
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