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This article is cited in 77 scientific papers (total in 77 papers)
Polynuclear complexes of copper(I) halides: coordination chemistry and catalytic transformations of alkynes
B. M. Mykhalichkoa, O. N. Temkinb, M. G. Mys'kiva a Ivan Franko National University of L'viv
b M. V. Lomonosov Moscow State Academy of Fine Chemical Technology
Abstract:
Characteristic features of the coordination chemistry of Cu(I) and mechanisms of catalytic conversions of alkynes in the CuCl–MCl–H2O–HC≡CR system (MCl is alkali metal or ammonium chloride or amine hydrochloride; R=H, CH2OH, CH=CH2, etc.) are analysed based on studies of the compositions and structures of copper(I) chloride (bromide) complexes, alkyne π-complexes and ethynyl organometallic polynuclear compounds formed in this system in solutions and in the crystalline state. The role of polynuclear complexes in various reactions of alkynes is discussed. The bibliography includes 149 references.
Received: 03.07.2000
Citation:
B. M. Mykhalichko, O. N. Temkin, M. G. Mys'kiv, “Polynuclear complexes of copper(I) halides: coordination chemistry and catalytic transformations of alkynes”, Usp. Khim., 69:11 (2000), 1042–1070; Russian Chem. Reviews, 69:11 (2000), 957–984
Linking options:
https://www.mathnet.ru/eng/rcr1552https://doi.org/10.1070/RC2000v069n11ABEH000609 https://www.mathnet.ru/eng/rcr/v69/i11/p1042
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