Abstract:
The published data are surveyed and a comparative crystal-chemical analysis is presented for the structures of compounds containing mercury in low oxidation states as cluster Hgn groups with covalent Hg–Hg bonds. The geometry of compounds with Hg–Hg and Hg–X bonds (X = O, S, Se, N or Hal) is analysed and the types of coordination of mercury ions, the packing modes and the relationships between structural units are described. The crystallographic and crystal-chemical data for mercury compounds are given. The bibliography includes 124 references.
Received: 14.01.1999
Bibliographic databases:
Document Type:
Article
UDC:
548.735
Language: English
Original paper language: Russian
Citation:
N. V. Pervukhina, S. A. Magarill, S. V. Borisov, G. V. Romanenko, N. A. Pal'chik, “Crystal chemistry of compounds containing mercury in low oxidation states”, Usp. Khim., 68:8 (1999), 683–707; Russian Chem. Reviews, 68:8 (1999), 615–636
Linking options:
https://www.mathnet.ru/eng/rcr1477
https://doi.org/10.1070/RC1999v068n08ABEH000507
https://www.mathnet.ru/eng/rcr/v68/i8/p683
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