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This article is cited in 26 scientific papers (total in 26 papers)
The problem of oxidation state stabilisation and some regularities of a Periodic system of the elements
Yu. M. Kiselev, Yu. D. Tret'yakov M. V. Lomonosov Moscow State University, Department of Chemistry
Abstract:
The general principles of the concept of oxidation state stabilisation are formulated. Problems associated with the preparation and provision of the highest valent forms of transition elements are considered. The empirical data concerning the synthesis of new compounds of rare-earth elements and d elements in unusually high oxidation states are analysed. The possibility of occurrence of the oxidation states + 9 and + 10 for some elements (for example, for iridium and platinum in tetraoxo ions) are discussed. Approaches to the realisation of these states are outlined and it is demonstrated that solid phases or matrices containing alkali metal cations are the most promising systems for the stabilisation of these high oxidation states. Selected thermodynamic features typical of metal halides and oxides and the regularities of the changes in the extreme oxidation states of d elements are considered. The bibliography includes 266 references.
Received: 01.12.1998
Citation:
Yu. M. Kiselev, Yu. D. Tret'yakov, “The problem of oxidation state stabilisation and some regularities of a Periodic system of the elements”, Usp. Khim., 68:5 (1999), 401–415; Russian Chem. Reviews, 68:5 (1999), 365–379
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https://www.mathnet.ru/eng/rcr1464https://doi.org/10.1070/RC1999v068n05ABEH000496 https://www.mathnet.ru/eng/rcr/v68/i5/p401
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