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This article is cited in 31 scientific papers (total in 31 papers)
Haloalkenes activated by geminal groups in reactions with N-nucleophiles
A. Yu. Rulev Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Abstract:
Reactions of nitrogen nucleophiles with haloalkenes in which the halogen atom occupies α-position with respect to an electron-withdrawing group are considered. Primary attention is devoted to the elucidation of the dependence of the reaction path on the nature of the nucleophile and substrate and on the reaction conditions. Possible mechanisms of nucleophilic substitution of vinylic halogen atoms in alkenes with activating and leaving groups attached to the same carbon atom are discussed. The bibliography includes 169 references.
Received: 09.06.1997
Citation:
A. Yu. Rulev, “Haloalkenes activated by geminal groups in reactions with N-nucleophiles”, Usp. Khim., 67:4 (1998), 317–332; Russian Chem. Reviews, 67:4 (1998), 279–293
Linking options:
https://www.mathnet.ru/eng/rcr1401https://doi.org/10.1070/RC1998v067n04ABEH000372 https://www.mathnet.ru/eng/rcr/v67/i4/p317
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