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This article is cited in 15 scientific papers (total in 15 papers)
2-Cyanoacrylates. Synthesis, properties and applications
Yu. G. Gololobova, W. Gruberb a A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
b Henkel Kommandit Gesellschaft auf Aktien, Germany
Abstract:
Methods for the synthesis, properties and applications of alkyl 2-cyanoacrylates are surveyed. The reactions of alkyl 2-cyanoacrylates with various nucleophiles (thiols, alcohols, diols, hydrogen sulfide, phosphines, etc.) including a new reaction involving insertion of isocyanates and isothiocyanates into the C=C bonds in the adducts of alkyl 2-cyanoacrylates with trialkylphosphines are considered. The prospects for the use of alkyl 2-cyanoacrylates in organic synthesis, in the chemistry of polymers and in the chemistry of adhesives are described. The bibliography includes 117 references.
Received: 04.04.1997
Citation:
Yu. G. Gololobov, W. Gruber, “2-Cyanoacrylates. Synthesis, properties and applications”, Usp. Khim., 66:11 (1997), 1054–1063; Russian Chem. Reviews, 66:11 (1997), 953–962
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https://www.mathnet.ru/eng/rcr1377https://doi.org/10.1070/RC1997v066n11ABEH000321 https://www.mathnet.ru/eng/rcr/v66/i11/p1054
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