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This article is cited in 57 scientific papers (total in 57 papers)
Competitive coordination: ambident ligands in the modern chemistry of metal complexes
A. D. Garnovskiia, D. A. Garnovskiia, I. S. Vasil'chenkoa, A. S. Burlova, A. P. Sadimenkob, I. D. Sadekova a Institute of Physical and Organic Chemistry at Rostov State University
b University of the Orange Free State, Republic of South Africa
Abstract:
Data on the problem of competitive coordination, obtained mainly during the last 10 years, are surveyed and treated systematically. The competitive binding of metals in complexes of bi- and poly-dentate ligand systems — simple diatomic and triatomic compounds (N2, O2, CO, CO2, CS2, etc.), ambident anions (CN-, NCX-, NO2-, SO32-, etc.), and neutral aliphatic, aromatic, and heterocyclic compounds, including chelating organic ligands — is examined. Attention is specially concentrated on nontraditional ways in which typical ligand systems are coordinated and on regioselective synthesis as a method for the specific synthesis of metal complexes with a specified location of the coordinate bond. The bibliography includes 575 references.
Received: 24.06.1996
Citation:
A. D. Garnovskii, D. A. Garnovskii, I. S. Vasil'chenko, A. S. Burlov, A. P. Sadimenko, I. D. Sadekov, “Competitive coordination: ambident ligands in the modern chemistry of metal complexes”, Usp. Khim., 66:5 (1997), 434–462; Russian Chem. Reviews, 66:5 (1997), 389–416
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https://www.mathnet.ru/eng/rcr1349https://doi.org/10.1070/RC1997v066n05ABEH000258 https://www.mathnet.ru/eng/rcr/v66/i5/p434
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