Abstract:
Published data concerning the quantitative estimation of the inductive interaction of functional groups in organic and organoelement compounds are systematically described. Studies carried out by the authors and devoted to the elaboration of a new model of the inductive effect, permitting theoretical calculation of inductive constants of various substituents at any reactive centre, are surveyed. The possibility of using this approach to solve some important theoretical problems associated with the inductive effect such as the inductive influence in organoelement compounds and the inductive effects of alkyl groups is discussed.The bibliography includes 132 references.
Received: 30.01.1996
Bibliographic databases:
Document Type:
Article
UDC:
541.636:541.127
Language: English
Original paper language: Russian
Citation:
A. R. Cherkasov, V. I. Galkin, R. A. Cherkasov, “The problem of the quantitative evaluation of the inductive effect: correlation analysis”, Usp. Khim., 65:8 (1996), 695–711; Russian Chem. Reviews, 65:8 (1996), 641–656
Linking options:
https://www.mathnet.ru/eng/rcr1307
https://doi.org/10.1070/RC1996v065n08ABEH000227
https://www.mathnet.ru/eng/rcr/v65/i8/p695
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