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This article is cited in 66 scientific papers (total in 66 papers)
Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds
Yu. V. Tomilova, V. A. Dokitchevb, U. M. Dzhemilevc, O. M. Nefedova a N. D. Zelinskii Institute of Organic Chemistry, Moscow
b Institute of Organic Chemistry, Ufa Scientific Centre of RAS
c Institute of Oil Chemistry and Catalyse, Academy of Sciences of Bashkortostan, Ufa
Abstract:
The principal advances and trends in the application of diazomethane as a methylenating agent in synthetic chemistry using transition and non-transition metal compounds as catalysts are surveyed and analysed. The catalytic reactions of diazomethane with olefins, acethylenes, aromatic compounds, ketones, alcohols and amines are examined. A systematic account is given of data concerning the influence of the structure of the initial substrates and of the nature of the catalyst components on the regio- and stereo-selectivity of the reactions considered. The possibilities of the catalytic conversion by diazomethane (generated in situ) of unsaturated compounds into cyclopropane derivatives are considered. The bibliography includes 284 references.
Received: 17.06.1993
Citation:
Yu. V. Tomilov, V. A. Dokitchev, U. M. Dzhemilev, O. M. Nefedov, “Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds”, Usp. Khim., 62:9 (1993), 847–886; Russian Chem. Reviews, 62:9 (1993), 799–838
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https://www.mathnet.ru/eng/rcr1123https://doi.org/10.1070/RC1993v062n09ABEH000048 https://www.mathnet.ru/eng/rcr/v62/i9/p847
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