N. B. Mikheev, L. N. Auerman, I. A. Rumer, A. N. Kamenskaya, M. Z. Kazakevich, “The anomalous stabilisation of the oxidation state 2+ of lanthanides and actinides”, Usp. Khim., 61:10 (1992), 1805–1821; Russian Chem. Reviews, 61:10 (1992), 990

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Russian Chemical Reviews, 1992, Volume 61, Issue 10, Pages 990–998
DOI: https://doi.org/10.1070/RC1992v061n10ABEH001011 (Mi rcr1059)

This article is cited in 37 scientific papers (total in 37 papers)

The anomalous stabilisation of the oxidation state 2+ of lanthanides and actinides

N. B. Mikheev, L. N. Auerman, I. A. Rumer, A. N. Kamenskaya, M. Z. Kazakevich

Institute of Physical Chemistry, Russian Academy of Sciences, Moscow

English full-text Citations (37)

DOI: https://doi.org/10.1070/RC1992v061n10ABEH001011

Abstract: The present review deals with the anomalous stabilisation of the oxidation state 2+ of a number of lanthanides and actinides. This stabilisation of the oxidation state 2+ is due to the lowering of the energy of a d-orbital as a result of crystal field splitting in the ligand field and d-electron participation in chemical bonding.
The bibliography includes 68 references.

Received: 08.05.1992

Russian version:
Uspekhi Khimii, 1992, Volume 61, Issue 10, Pages 1805–1821
DOI: https://doi.org/10.1070/RC1992v061n10ABEH001011

Bibliographic databases:

Document Type: Article

UDC: 541.2+546.65+546.66+546.799

Language: English

Original paper language: Russian

Citation: N. B. Mikheev, L. N. Auerman, I. A. Rumer, A. N. Kamenskaya, M. Z. Kazakevich, “The anomalous stabilisation of the oxidation state 2+ of lanthanides and actinides”, Usp. Khim., 61:10 (1992), 1805–1821; Russian Chem. Reviews, 61:10 (1992), 990–998

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https://doi.org/10.1070/RC1992v061n10ABEH001011

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This publication is cited in the following 37 articles:

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