Abstract:
The results of non-empirical quantum-chemical calculations for silicon, phosphorus, and sulfur compounds of different structure are discussed. Qualitative orbital models, which establish a relation between the distribution of electrons and molecular structure and properties, are analysed. A general definition of stereoelectronic effects is presented. The bibliography includes 176 references.
Bibliographic databases:
Document Type:
Article
UDC:
541.5
Language: English
Original paper language: Russian
Citation:
A. A. Korkin, “Stereoelectronic effects in silicon, phosphorus, and sulfur molecules. Quantum-chemical calculations and qualitative orbital models”, Usp. Khim., 61:5 (1992), 865–882; Russian Chem. Reviews, 61:5 (1992), 473–483
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https://www.mathnet.ru/eng/rcr1027
https://doi.org/10.1070/RC1992v061n05ABEH000957
https://www.mathnet.ru/eng/rcr/v61/i5/p865
This publication is cited in the following 14 articles:
V. Jouikov, D. Fattahova, Electrochimica Acta, 43:12-13 (1998), 1811
V. F. Mironov, I. V. Konovalova, L. M. Burnaeva, E. N. Ofitserov, Russian Chem. Reviews, 65:11 (1996), 935–972
Anatoli A. Korkin, Anna Balkova, Rodney J. Bartlett, Russell J. Boyd, Paul von Rague Schleyer, J. Phys. Chem., 100:14 (1996), 5702
R. P. Kamalesh Babu, K. Aparna, S. S. Krishnamurthy, M. Nethaji, Phosphorus, Sulfur, and Silicon and the Related Elements, 103:1-4 (1995), 39
G. Becker, B. Eschbach, O. Mundt, N. Seidler, Zeitschrift anorg allge chemie, 620:8 (1994), 1381
Vladimir M. Bzhezovsky, Vladimir V. Penkovsky, Alexander B. Rozhenko, Svetlana V. Iksanova, Natalia V. Kondratenko, Lev M. Yagupolsky, Journal of Fluorine Chemistry, 69:1 (1994), 41
È. I. Brodskaya, G. V. Ratovskii, M. G. Voronkov, Russian Chem. Reviews, 62:10 (1993), 919–933
Ramaswamy Murugavel, Setharampattu S. Krishnamurthy, Munirathinam Nethaji, J. Chem. Soc., Dalton Trans., 1993, no. 24, 3635
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