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This article is cited in 1 scientific paper (total in 1 paper)
Alexey Borisov Memorial Volume
The Influence of a Parameter that Controls the Asymmetry
of a Potential Energy Surface with an Entrance Channel
and Two Potential Wells
Makrina Agaoglouab, Matthaios Katsanikasca, Stephen Wigginsa a School of Mathematics, University of Bristol,
Fry Building, Woodland Road, BS8 1UG Bristol, United Kingdom
b Instituto de Ciencias Matematicas,
C/Nicolas Cabrera 13-15, Campus Cantoblanco, 28049 Madrid, Spain
c Research Center for Astronomy and Applied Mathematics, Academy of Athens,
Soranou Efesiou 4, GR-11527 Athens, Greece
Abstract:
In this paper we study an asymmetric valley-ridge inflection point (VRI) potential,
whose energy surface (PES) features two sequential index-1 saddles (the upper and the lower),
with one saddle having higher energy than the other, and two potential wells separated by the
lower index-1 saddle. We show how the depth and the flatness of our potential changes as we
modify the parameter that controls the asymmetry as well as how the branching ratio (ratio
of the trajectories that enter each well) is changing as we modify the same parameter and its
correlation with the area of the lobes as they have been formed by the stable and unstable
manifolds that have been extracted from the gradient of the LD scalar fields.
Keywords:
phase space structure, Lagrangian descriptors, chemical reaction dynamics, valley
ridge inflection point potential.
Received: 15.03.2021 Accepted: 26.11.2021
Citation:
Makrina Agaoglou, Matthaios Katsanikas, Stephen Wiggins, “The Influence of a Parameter that Controls the Asymmetry
of a Potential Energy Surface with an Entrance Channel
and Two Potential Wells”, Regul. Chaotic Dyn., 27:2 (2022), 232–241
Linking options:
https://www.mathnet.ru/eng/rcd1162 https://www.mathnet.ru/eng/rcd/v27/i2/p232
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Abstract page: | 78 | References: | 17 |
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