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Kvantovaya Elektronika, 1981, Volume 8, Number 3, Pages 565–570 (Mi qe6325)  

This article is cited in 6 scientific papers (total in 6 papers)

Isotopically selective dissociation of small molecules exposed to pulsed CO2 laser radiation

T. G. Abzianidze, A. S. Egiazarov, A. K. Petrov, Yu. N. Samsonov
Abstract: It is found that the multiphoton dissociation yield of small, particularly light, molecules (HFCO/DFCO, CHF3/CDF3, SiH4, 12CF3Br/13CF3Br, CF3I) may be increased many times by adding appreciable quantities of buffer gases (Ar, He, NO). In this respect, multiphoton dissociation of small molecules differs from the dissociation of polyatomic molecules (SF6, C6F6, CF3COCF3) for which the dissociation yield decreases when buffer gases are added. The effective isotopic selectivity of the dissociation of small molecules may either decrease or increase when buffer gases are added depending on the isotope shift, the laser radiation frequency used, and on the pressures of the isotopic molecule mixture and the buffer gas.
Received: 26.06.1980
English version:
Soviet Journal of Quantum Electronics, 1981, Volume 11, Issue 3, Pages 343–346
DOI: https://doi.org/10.1070/QE1981v011n03ABEH006325
Bibliographic databases:
Document Type: Article
UDC: 541.141.7+621.039.335
PACS: 33.80.Gj
Language: Russian


Citation: T. G. Abzianidze, A. S. Egiazarov, A. K. Petrov, Yu. N. Samsonov, “Isotopically selective dissociation of small molecules exposed to pulsed CO2 laser radiation”, Kvantovaya Elektronika, 8:3 (1981), 565–570 [Sov J Quantum Electron, 11:3 (1981), 343–346]
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  • https://www.mathnet.ru/eng/qe/v8/i3/p565
  • This publication is cited in the following 6 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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