Multifrequency stimulated Raman scattering of light in a calcite single crystal

Using pulses of multifrequency stimulated Raman scattering (SRS) in calcite, nonlinear photoluminescence in a stilbene molecular crystal is excited. When multifrequency SRS is excited by the radiation of a Nd³⁺ : YAG laser with a wavelength of 1064 nm, eleven anti-Stokes components are observed in the visible spectrum with an average frequency shift of 1086 cm^-1 between them. Using the second harmonic of the Nd³⁺ : YAG laser radiation allowed three anti-Stokes and four Stokes components to be recorded. The large spectral range of the frequency comb facilitated effective reduction in the duration and increase in the intensity of the radiation pulse of multifrequency SRS.