Parametric stimulated Raman scattering in barium nitrate crystals

The spectra of multifrequency parametric stimulated Raman scattering in a barium nitrate single crystal is investigated. When this single crystal is excited by ultrashort (80 ps) YAG : Nd³⁺ laser pulses with a wavelength of 1064 nm, a frequency comb of eight anti-Stokes components is observed in the visible spectral range. The Raman satellites are due to the totally symmetric vibrational modes of barium nitrate single crystal. The frequencies of the corresponding Raman Stokes components in the IR range (from 1193 to 9662 nm) are calculated. The results of the study open the way to form an array of laser frequencies from the IR to green spectral range with a period of 1047 cm^-1.