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Kvantovaya Elektronika, 1976, Volume 3, Number 10, Pages 2232–2237 (Mi qe11930)  

Relationship between stimulated emission and reaction mechanism in chemical lasers utilizing mixtures of chlorine flourides and hydrogen

N. F. Chebotarev, S. Ya. Pshezhetskiĭ
Abstract: An analysis is made of the principal elementary processes resulting in stimulated emission from ClF3+H2 and ClF5+H2 systems. A study of pulsed stimulated emission from HF and HCl in mixtures containing also HCl, Cl2, and ClF shows that the intermediate product ClF is a part of a laser reaction chain. The process H+ClF→HCl*+F is much faster than H+ClF3 or H+ClF5. It is found that "autocatalysis" by HCl molecules, which are also an intermediate product, is possible in the ClF5+H2 system.
Received: 12.03.1976
English version:
Soviet Journal of Quantum Electronics, 1976, Volume 6, Issue 10, Pages 1214–1217
DOI: https://doi.org/10.1070/QE1976v006n10ABEH011930
Document Type: Article
UDC: 621.375.826:541.127:546
PACS: 51.70.+f, 82.40.Tc
Language: Russian


Citation: N. F. Chebotarev, S. Ya. Pshezhetskiĭ, “Relationship between stimulated emission and reaction mechanism in chemical lasers utilizing mixtures of chlorine flourides and hydrogen”, Kvantovaya Elektronika, 3:10 (1976), 2232–2237 [Sov J Quantum Electron, 6:10 (1976), 1214–1217]
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