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Pisma v Zhurnal Tekhnicheskoi Fiziki, 2021, Volume 47, Issue 11, Pages 51–54
DOI: https://doi.org/10.21883/PJTF.2021.11.51010.18721
(Mi pjtf4779)
 

Impedance spectroscopy of charge conducting composite materials based on microfibers of polyvinylidene fluoride copolymer with trifluoroethylene modified with polypyrrole

V. M. Kapralovaa, I. Yu. Sapurinab, N. T. Sudara, A. A. Tretiakova, O. Gryshkovc, B. Glasmacherc

a Peter the Great St. Petersburg Polytechnic University
b Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg
c Institute for Multiphase Processes, Leibniz Universität Hannover, Garbsen, Germany
Abstract: The impedance spectra of composite nonwoven materials based on nano- and microfibers of polyvinylidene fluoride copolymer with trifluoroethylene modified with polypyrrole with various degrees of doping are studied in the frequency range 1 $\times$ 10$^{3}$ – 1.5 $\times$ 10$^{7}$ Hz. It is found that an increase in the degree of doping of the polypyrrole coating of nanofibers leads to a decrease in the imaginary and real components of the electrical impedance. Regardless of their size, the shape of the hodographs is close to the arc of a circle based on the axis of the real component, which allows considering the studied material as a nanocomposite polymer electrolyte, the dielectric characteristics of which can be reversibly changed.
Keywords: nonwoven materials, polypyrrole, polyvinylidene fluoride, impedance.
Funding agency Grant number
Ministry of Education and Science of the Russian Federation 075-15-2020-934
World-Class Scientific Center at St. Petersburg Polytechnic University, Advanced Digital Technologies section 075-15-2020-934
The research was carried out with the financial support of the Ministry of Education and Science of the Russian Federation as part of the program World-Class Scientific Center at St. Petersburg Polytechnic University, Advanced Digital Technologies section, agreement no. 075-15-2020-934 of November 17, 2020.
Received: 29.01.2021
Revised: 12.03.2021
Accepted: 15.03.2021
English version:
Technical Physics Letters, 2021, Volume 47, Issue 8, Pages 561–564
DOI: https://doi.org/10.1134/S1063785021060109
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: V. M. Kapralova, I. Yu. Sapurina, N. T. Sudar, A. A. Tretiakov, O. Gryshkov, B. Glasmacher, “Impedance spectroscopy of charge conducting composite materials based on microfibers of polyvinylidene fluoride copolymer with trifluoroethylene modified with polypyrrole”, Pisma v Zhurnal Tekhnicheskoi Fiziki, 47:11 (2021), 51–54; Tech. Phys. Lett., 47:8 (2021), 561–564
Citation in format AMSBIB
\Bibitem{KapSapSud21}
\by V.~M.~Kapralova, I.~Yu.~Sapurina, N.~T.~Sudar, A.~A.~Tretiakov, O.~Gryshkov, B.~Glasmacher
\paper Impedance spectroscopy of charge conducting composite materials based on microfibers of polyvinylidene fluoride copolymer with trifluoroethylene modified with polypyrrole
\jour Pisma v Zhurnal Tekhnicheskoi Fiziki
\yr 2021
\vol 47
\issue 11
\pages 51--54
\mathnet{http://mi.mathnet.ru/pjtf4779}
\crossref{https://doi.org/10.21883/PJTF.2021.11.51010.18721}
\elib{https://elibrary.ru/item.asp?id=46321614}
\transl
\jour Tech. Phys. Lett.
\yr 2021
\vol 47
\issue 8
\pages 561--564
\crossref{https://doi.org/10.1134/S1063785021060109}
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