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Fizika i Tekhnika Poluprovodnikov, 2016, Volume 50, Issue 6, Pages 854–858 (Mi phts6452)  

This article is cited in 5 scientific papers (total in 5 papers)

Manufacturing, processing, testing of materials and structures

The modification of BaCe$_{0.5}$Zr$_{0.3}$Y$_{0.2}$O$_{3-\delta}$ with copper oxide: Effect on the structural and transport properties

J. G. Lyagaevaa, G. K. Vdovina, I. V. Nikolaenkobc, D. A. Medvedevac, A. K. Demina

a Institute of High-Temperature Electrochemistry, RAS, Yekaterinburg, Russia
b Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Ekaterinburg
c Ural Federal University, Ekaterinburg
Full-text PDF (970 kB) Citations (5)
Abstract: The effect of the content of CuO additive on the sinterability, phase composition, microstructure, and electrical properties of BaCe$_{0.5}$Zr$_{0.3}$Y$_{0.2}$O$_{3-\delta}$ proton-conducting material is studied. Ceramic samples were produced by the citrate–nitrate synthesis method with the addition of 0, 0.25, 0.5, and 1% CuO. It is shown that the relative density of the samples containing 0.5 and 1% CuO is higher than 94% at a sintering temperature of 1450°C, whereas the relative density of the material is no higher than 85% at a lower content of the sintering additive. From the data of X-ray diffraction analysis and scanning electron microscopy, it is established that the introduction of a small CuO content (0.25%) is inadequate for single-phase and high-dense ceramics to be formed. The conductivity and scanning electron microscopy data show that the sample with BaCe$_{0.5}$Zr$_{0.3}$Y$_{0.2}$O$_{3-\delta}$ + 0.5% CuO composition possesses high total and ionic conductivities as well as a high degree of microstructural stability after hydrogen reduction of the ceramics. The citrate–nitrate method modified by the introduction of a small CuO content can be recommended for the production of single-phase, gas-tight, and high-conductivity electrolytes based on both BaCeO$_{3}$ and BaZrO$_{3}$.
Received: 03.11.2015
Accepted: 18.11.2015
English version:
Semiconductors, 2016, Volume 50, Issue 6, Pages 839–843
DOI: https://doi.org/10.1134/S1063782616060142
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: J. G. Lyagaeva, G. K. Vdovin, I. V. Nikolaenko, D. A. Medvedev, A. K. Demin, “The modification of BaCe$_{0.5}$Zr$_{0.3}$Y$_{0.2}$O$_{3-\delta}$ with copper oxide: Effect on the structural and transport properties”, Fizika i Tekhnika Poluprovodnikov, 50:6 (2016), 854–858; Semiconductors, 50:6 (2016), 839–843
Citation in format AMSBIB
\Bibitem{LyaVdoNik16}
\by J.~G.~Lyagaeva, G.~K.~Vdovin, I.~V.~Nikolaenko, D.~A.~Medvedev, A.~K.~Demin
\paper The modification of BaCe$_{0.5}$Zr$_{0.3}$Y$_{0.2}$O$_{3-\delta}$ with copper oxide: Effect on the structural and transport properties
\jour Fizika i Tekhnika Poluprovodnikov
\yr 2016
\vol 50
\issue 6
\pages 854--858
\mathnet{http://mi.mathnet.ru/phts6452}
\elib{https://elibrary.ru/item.asp?id=27368925}
\transl
\jour Semiconductors
\yr 2016
\vol 50
\issue 6
\pages 839--843
\crossref{https://doi.org/10.1134/S1063782616060142}
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  • This publication is cited in the following 5 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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    Fizika i Tekhnika Poluprovodnikov Fizika i Tekhnika Poluprovodnikov
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