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Fizika i Tekhnika Poluprovodnikov, 2019, Volume 53, Issue 12, Pages 1664–1668
DOI: https://doi.org/10.21883/FTP.2019.12.48623.9165
(Mi phts5331)
 

Amorphous, glassy, organic semiconductors

Charge transfer in gap structures based on the chalcogenide system (As$_{2}$Se$_{3}$)$_{100-x}$Bi$_{x}$

R. A. Castroa, S. D. Khaninab, A. P. Smirnova, A. A. Kononova

a Herzen State Pedagogical University of Russia, St. Petersburg
b Budyonny Military Academy of Communications, St. Petersburg, Russia
Abstract: The results of investigating charge-transfer processes in thin layers of a vitreous system (As$_{2}$Se$_{3}$)$_{100-x}$Bi$_{x}$ are presented. A power-law dependence of the conductivity on the frequency and a decrease in the exponent s with increasing temperature are found. Charge transfer is a thermally activated process with two regions in the temperature dependence of the conductivity with the activation energies $E_1$ = 0.12 $\pm$ 0.01 eV and $E_2$ = 0.23 $\pm$ 0.01 eV, respectively. The results are explained in terms of the correlated barrier hopping (CBH) model of hopping conductivity in disordered systems. The main microparameters of the system are calculated: the density of localized states $(N)$, the hopping length $(R_\omega)$, and the largest height of the potential barrier $(W_M)$.
Keywords: vitreous system vitreous system (As$_{2}$Se$_{3}$)$_{100-x}$Bi$_{x}$, dielectric spectroscopy, conductivity, dielectric spectroscopy, conductivity, gap structures, X-ray diffraction analysis.
Funding agency Grant number
Ministry of Education and Science of the Russian Federation 16.2811.2017/ПЧ
This work was supported by the Ministry of Education and Science of the Russian Federation in the framework of the state task (project no. 16.2811.2017/PCh).
Received: 21.05.2019
Revised: 01.07.2019
Accepted: 10.07.2019
English version:
Semiconductors, 2019, Volume 53, Issue 12, Pages 1646–1650
DOI: https://doi.org/10.1134/S1063782619160127
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: R. A. Castro, S. D. Khanin, A. P. Smirnov, A. A. Kononov, “Charge transfer in gap structures based on the chalcogenide system (As$_{2}$Se$_{3}$)$_{100-x}$Bi$_{x}$”, Fizika i Tekhnika Poluprovodnikov, 53:12 (2019), 1664–1668; Semiconductors, 53:12 (2019), 1646–1650
Citation in format AMSBIB
\Bibitem{CasKhaSmi19}
\by R.~A.~Castro, S.~D.~Khanin, A.~P.~Smirnov, A.~A.~Kononov
\paper Charge transfer in gap structures based on the chalcogenide system (As$_{2}$Se$_{3}$)$_{100-x}$Bi$_{x}$
\jour Fizika i Tekhnika Poluprovodnikov
\yr 2019
\vol 53
\issue 12
\pages 1664--1668
\mathnet{http://mi.mathnet.ru/phts5331}
\crossref{https://doi.org/10.21883/FTP.2019.12.48623.9165}
\elib{https://elibrary.ru/item.asp?id=41848192}
\transl
\jour Semiconductors
\yr 2019
\vol 53
\issue 12
\pages 1646--1650
\crossref{https://doi.org/10.1134/S1063782619160127}
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