|
Amorphous, glassy, organic semiconductors
Charge transfer in gap structures based on the chalcogenide system (As$_{2}$Se$_{3}$)$_{100-x}$Bi$_{x}$
R. A. Castroa, S. D. Khaninab, A. P. Smirnova, A. A. Kononova a Herzen State Pedagogical University of Russia, St. Petersburg
b Budyonny Military Academy of Communications, St. Petersburg, Russia
Abstract:
The results of investigating charge-transfer processes in thin layers of a vitreous system (As$_{2}$Se$_{3}$)$_{100-x}$Bi$_{x}$ are presented. A power-law dependence of the conductivity on the frequency and a decrease in the exponent s with increasing temperature are found. Charge transfer is a thermally activated process with two regions in the temperature dependence of the conductivity with the activation energies $E_1$ = 0.12 $\pm$ 0.01 eV and $E_2$ = 0.23 $\pm$ 0.01 eV, respectively. The results are explained in terms of the correlated barrier hopping (CBH) model of hopping conductivity in disordered systems. The main microparameters of the system are calculated: the density of localized states $(N)$, the hopping length $(R_\omega)$, and the largest height of the potential barrier $(W_M)$.
Keywords:
vitreous system vitreous system (As$_{2}$Se$_{3}$)$_{100-x}$Bi$_{x}$, dielectric spectroscopy, conductivity, dielectric spectroscopy, conductivity, gap structures, X-ray diffraction analysis.
Received: 21.05.2019 Revised: 01.07.2019 Accepted: 10.07.2019
Citation:
R. A. Castro, S. D. Khanin, A. P. Smirnov, A. A. Kononov, “Charge transfer in gap structures based on the chalcogenide system (As$_{2}$Se$_{3}$)$_{100-x}$Bi$_{x}$”, Fizika i Tekhnika Poluprovodnikov, 53:12 (2019), 1664–1668; Semiconductors, 53:12 (2019), 1646–1650
Linking options:
https://www.mathnet.ru/eng/phts5331 https://www.mathnet.ru/eng/phts/v53/i12/p1664
|
Statistics & downloads: |
Abstract page: | 40 | Full-text PDF : | 18 |
|