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This article is cited in 2 scientific papers (total in 2 papers)
Optical materials
Monomers with a high refraction index based on acryloyl derivatives of spirocyclic piperidin-4-one thioacetals
V. S. Basistyiab, A. D. Bukhtoyarovaa, E. V. Vasil'eva, V. V. Shelkovnikova a Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
b Novosibirsk State University, Novosibirsk, 630090, Russia
Abstract:
Dithioazaspiroheterocyclic derivatives are synthesized by condensing dithiols with piperidin-4-one in the presence of catalytic amounts of Lewis acids. Acrylic dithioazaspiroheterocyclic derivatives are obtained by the reaction with acryloyl chloride. The polymerization of monomers yields transparent polymer films of optical quality. The refractive indices for the synthesized monomers and polymers are in the range of $n$ = 1.59–1.64.
Received: 03.12.2017 Revised: 20.03.2018
Citation:
V. S. Basistyi, A. D. Bukhtoyarova, E. V. Vasil'ev, V. V. Shelkovnikov, “Monomers with a high refraction index based on acryloyl derivatives of spirocyclic piperidin-4-one thioacetals”, Optics and Spectroscopy, 125:1 (2018), 79–84; Optics and Spectroscopy, 125:1 (2018), 82–87
Linking options:
https://www.mathnet.ru/eng/os959 https://www.mathnet.ru/eng/os/v125/i1/p79
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