Abstract:
Dithioazaspiroheterocyclic derivatives are synthesized by condensing dithiols with piperidin-4-one in the presence of catalytic amounts of Lewis acids. Acrylic dithioazaspiroheterocyclic derivatives are obtained by the reaction with acryloyl chloride. The polymerization of monomers yields transparent polymer films of optical quality. The refractive indices for the synthesized monomers and polymers are in the range of $n$ = 1.59–1.64.
Citation:
V. S. Basistyi, A. D. Bukhtoyarova, E. V. Vasil'ev, V. V. Shelkovnikov, “Monomers with a high refraction index based on acryloyl derivatives of spirocyclic piperidin-4-one thioacetals”, Optics and Spectroscopy, 125:1 (2018), 79–84; Optics and Spectroscopy, 125:1 (2018), 82–87
\Bibitem{BasBukVas18}
\by V.~S.~Basistyi, A.~D.~Bukhtoyarova, E.~V.~Vasil'ev, V.~V.~Shelkovnikov
\paper Monomers with a high refraction index based on acryloyl derivatives of spirocyclic piperidin-4-one thioacetals
\jour Optics and Spectroscopy
\yr 2018
\vol 125
\issue 1
\pages 79--84
\mathnet{http://mi.mathnet.ru/os959}
\crossref{https://doi.org/10.21883/OS.2018.07.46270.285-17}
\elib{https://elibrary.ru/item.asp?id=35270042}
\transl
\jour Optics and Spectroscopy
\yr 2018
\vol 125
\issue 1
\pages 82--87
\crossref{https://doi.org/10.1134/S0030400X18070044}
Linking options:
https://www.mathnet.ru/eng/os959
https://www.mathnet.ru/eng/os/v125/i1/p79
This publication is cited in the following 3 articles:
Evgenii Vasiliev, Alexandra Bukhtoyarova, Vladimir Shelkovnikov, Viktoria Berezhnaya, Inna Shundrina, “Synthesis and optical properties of monomers and polymers with high refractive indexes based on piperidone thioacetals”, Polymer Engineering & Sci, 2025
Vladimir Shelkovnikov, Evgenii Vasiliev, Dmitry Derevyanko, Alexandra Bukhtoyarova, Viktoria Berezhnaya, Inna Shundrina, “The holographic properties of photopolymers on the base of oxygen- and sulfur-containing spirocyclic monomers”, J Mater Sci, 58:2 (2023), 983
D. I. Derevyanko, V. S. Basistyi, V. V. Shelkovnikov, I. K. Shundrina, A. D. Bukhtoyarova, G. E. Sal'nikov, V. N. Berezhnaya, A. A. Chernonosov, “Hybrid Photopolymer Material Based on (8-Acryloyl-1,4-dithia-8-azaspiro[4.5]decan-2-yl)methyl Acrylate and Thiol-Siloxane Component for Recording Microstructures: Synthesis and Optical and Thermomechanical Properties”, Polym. Sci. Ser. B, 62:5 (2020), 509