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This article is cited in 3 scientific papers (total in 3 papers)
Spectroscopy of condensed matter
Crystal structure and luminescence of the [Dy(NO$_{3}$)$_{2}$(HMPA)$_{4}$](NO$_{3}$) complex
B. V. Bukvetskii, A. G. Mirochnik, P. A. Zhikhareva Institute of Chemistry, Far East Branch of the Russian Academy of Sciences, Vladivostok
Abstract:
The crystal structure of the [Dy(NO$_{3}$)$_{2}$(HMPA)$_{4}$](NO$_{3}$) complex (HMPA is hexamethylphosphorotriamide) is studied by X-ray diffraction analysis. The crystals are constructed of two crystallographically independent complex cations [Dy(NО$_{3}$)$_{2}$(HMPA)$_{4}$]$^{+}$ and outer-sphere [NO$_{3}$]$^{-1}$ groups. The structure is represented by separate С$_{24}$Н$_{72}$DyN$_{15}$O$_{13}$P$_{4}$ complexes bound by van der Waals interactions with pronounced layered morphology. The coordination polyhedron of Dy(III) with coordination number 8 is represented by a distorted trigonal prism with two centered square faces. The results of investigation of the luminescent properties in the visible and near-IR regions are presented.
Received: 05.09.2018 Revised: 05.11.2018 Accepted: 08.11.2018
Citation:
B. V. Bukvetskii, A. G. Mirochnik, P. A. Zhikhareva, “Crystal structure and luminescence of the [Dy(NO$_{3}$)$_{2}$(HMPA)$_{4}$](NO$_{3}$) complex”, Optics and Spectroscopy, 126:3 (2019), 275–279; Optics and Spectroscopy, 126:3 (2019), 195–199
Linking options:
https://www.mathnet.ru/eng/os754 https://www.mathnet.ru/eng/os/v126/i3/p275
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