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This article is cited in 10 scientific papers (total in 10 papers)
Spectroscopy of condensed matter
Effect of polymer matrix on the luminescent properties of compositions doped with boron chelates
E. V. Fedorenkoa, A. A. Khrebtovb, A. G. Mirochnika, P. S. Nefedovb, L. A. Limb, V. A. Reutovb, I. S. Pavlovb, A. A. Sergeevc a Institute of Chemistry, Far East Branch of the Russian Academy of Sciences, Vladivostok
b Far Eastern Federal University, Vladivostok
c Institute for Automation and Control Processes, Far Eastern Branch of the Russian Academy of Sciences, Vladivostok
Abstract:
Polymer luminescent compositions based on polystyrene (PS), polycarbonate (PC) and polymethyl methacrylate (PMMA) doped with boron difluoride dibenzoylmethanate (DBMBF$_2$), boron difluoride anthracenoylacetonate (AntAcBF$_2$) and their mixture were investigated. Composition based on PS has a maximum quantum yield of luminescence. The role of PS in increasing the efficiency of energy transfer from the donor (DBMBF$_2$) to the acceptor (AntAcBF$_2$) is revealed, which is due to the formation of exciplexes between DBMBF$_2$ and phenyl rings of PS.
Keywords:
$\beta$-diketonates boron difluoride, boron difluoride dibenzoylmethanate, polymers, luminescence, exciplexes.
Received: 24.12.2018 Revised: 24.12.2018 Accepted: 07.05.2019
Citation:
E. V. Fedorenko, A. A. Khrebtov, A. G. Mirochnik, P. S. Nefedov, L. A. Lim, V. A. Reutov, I. S. Pavlov, A. A. Sergeev, “Effect of polymer matrix on the luminescent properties of compositions doped with boron chelates”, Optics and Spectroscopy, 127:3 (2019), 425–428; Optics and Spectroscopy, 127:3 (2019), 459–462
Linking options:
https://www.mathnet.ru/eng/os609 https://www.mathnet.ru/eng/os/v127/i3/p425
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