|
This article is cited in 5 scientific papers (total in 5 papers)
Spectroscopy of condensed matter
Crystal structure, luminescence, and triboluminescence of the complex [Eu$_{2}$(Quin)$_{4}$2H$_{2}$O2Dipy]$_{2}$(NO$_{3}$)$_{2}$H$_{2}$O
B. V. Bukvetskii, I. V. Kalinovskaya Institute of Chemistry, Far East Branch of the Russian Academy of Sciences, Vladivostok
Abstract:
An atomic structure of crystals of the complex [Eu$_{2}$(Quin)$_{4}$2Н$_{2}$O2Dipy]$_{2}$ $\cdot$ 2(NO$_{3}$) $\cdot$ Н$_{2}$O, (Quin, anion of quinaldic acid; Dipy, 2,2'-dipyridyl), which exhibited intense luminescence and triboluminescence, has been investigated via the X-ray diffraction analysis. The structure of crystals of the compound appeared to be of an islelike type and were represented by two separate crystallographically independent complex dimers, outer-sphere [NO$_{3}$]$^{-1}$-groups, and water molecules. Structural aspects of the formation of the luminescent and triboluminescent properties of the compound have been discussed. The role of cleavage planes at crystal destruction has been established.
Keywords:
europium(III) complexes, crystal structure, triboluminescence, luminescence.
Received: 21.08.2018 Revised: 21.08.2018 Accepted: 15.03.2019
Citation:
B. V. Bukvetskii, I. V. Kalinovskaya, “Crystal structure, luminescence, and triboluminescence of the complex [Eu$_{2}$(Quin)$_{4}$2H$_{2}$O2Dipy]$_{2}$(NO$_{3}$)$_{2}$H$_{2}$O”, Optics and Spectroscopy, 127:3 (2019), 412–419; Optics and Spectroscopy, 127:3 (2019), 446–453
Linking options:
https://www.mathnet.ru/eng/os607 https://www.mathnet.ru/eng/os/v127/i3/p412
|
Statistics & downloads: |
Abstract page: | 39 |
|