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Optics and Spectroscopy, 2019, Volume 127, Issue 5, Pages 730–735
DOI: https://doi.org/10.21883/OS.2019.11.48506.144-19
(Mi os543)
 

Spectroscopy and physics of atoms and molecules

Physically correct configuration spaces in the description of the internal dynamics of a rigid molecule

A. V. Burenin

Institute of Applied Physics of the Russian Academy of Sciences, 603950, Nizhny Novgorod, Russia
Abstract: A family of configuration spaces in the description of the internal dynamics of a rigid molecule has been considered. It has been shown that the requirement of the physical correctness of the description leads to serious restrictions for such spaces. In particular, only spaces satisfying the Eckart condition are allowed for a nonlinear rigid molecule.
Keywords: vibration, rotation, Eckart–Sayvetz conditions.
Funding agency Grant number
Ministry of Science and Higher Education of the Russian Federation 0035-2014-0006
This work was carried out in the framework of a state order to the Institute of Applied Physics of the Russian Academy of Sciences, project no. 0035-2014-0006.
Received: 18.04.2019
Revised: 03.07.3019
Accepted: 08.07.2019
English version:
Optics and Spectroscopy, 2019, Volume 127, Issue 5, Pages 792–797
DOI: https://doi.org/10.1134/S0030400X19110055
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: A. V. Burenin, “Physically correct configuration spaces in the description of the internal dynamics of a rigid molecule”, Optics and Spectroscopy, 127:5 (2019), 730–735; Optics and Spectroscopy, 127:5 (2019), 792–797
Citation in format AMSBIB
\Bibitem{Bur19}
\by A.~V.~Burenin
\paper Physically correct configuration spaces in the description of the internal dynamics of a rigid molecule
\jour Optics and Spectroscopy
\yr 2019
\vol 127
\issue 5
\pages 730--735
\mathnet{http://mi.mathnet.ru/os543}
\crossref{https://doi.org/10.21883/OS.2019.11.48506.144-19}
\elib{https://elibrary.ru/item.asp?id=41848413}
\transl
\jour Optics and Spectroscopy
\yr 2019
\vol 127
\issue 5
\pages 792--797
\crossref{https://doi.org/10.1134/S0030400X19110055}
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