Abstract:
Pulsed cathodoluminescence of undoped and ytterbium- and cerium-doped ceramic samples of yttrium–aluminum garnet and yttrium oxide is studied within the range of 220–850 nm in order to clarify the nature of their intrinsic luminescence centers. It is shown that these materials have three types of intrinsic centers, namely, (1) autolocalized excitons with a hole component (О$_{3}^{-2}$) molecular ions associated with cation vacancies) emitting a single band at $\lambda\approx$ 350 nm in yttrium oxide and a double band at $\lambda\approx$ 320 and 350 nm in yttrium–aluminum garnet, (2) $F$ centers emitting a broad band at $\lambda\approx$ 490 nm in yttrium oxide and at $\lambda$$\approx$ 510 nm in yttrium–aluminum garnet, and (3) Y = O bound radicals emitting a series of narrow bands in the range of 600–730 nm in both materials. It is shown that doping of these materials with ytterbium does not affect the first center characteristics but strongly changes the characteristics of the second and third centers.
Keywords:
pulsed cathodoluminescence, $F$ center, autolocalized exciton, annealing of ceramics.
Citation:
V. I. Solomonov, V. V. Osipov, V. A. Shitov, K. E. Luk'yashin, A. S. Bubnova, “Intrinsic luminescence centers in yttrium–aluminum garnet and yttrium oxide ceramics”, Optics and Spectroscopy, 128:1 (2020), 5–9; Optics and Spectroscopy, 128:1 (2020), 1–5
This publication is cited in the following 19 articles:
S. D. Plekhovich, A. D. Plekhovich, A. M. Kut'in, E. E. Rostokina, A. V. Budruev, T. Yu. Biryukova, “Quantum-Chemical Modeling of Dispersed Systems with the Yttrium Aluminum Garnet Base”, High Energy Chem, 58:4 (2024), 362
M. A. Girsova, I. N. Anfimova, L. N. Kurilenko, T. V. Antropova, “Vliyanie sootnosheniya Bi/Y na lyuminestsentnye svoistva vismutsoderzhaschikh kompozitsionnykh materialov na osnove silikatnykh poristykh stekol”, Fizika i himiâ stekla, 50:3 (2024), 70
C. D. Plekhovich, A. D. Plekhovich, A. M. Kutiin, E. E. Rostokina, A. V. Budruev, T. Yu. Biryukova, “Quantum-chemical modeling of dispersed systems with the yttrium aluminum garnet base”, Himiâ vysokih ènergij, 58:4 (2024), 245
M. A. Girsova, I. N. Anfimova, L. N. Kurilenko, T. V. Antropova, “Influence of the Bi/Y Ratio on the Luminescent Properties of Bismuth-Containing Composite Materials Based on Silicate Porous Glasses”, Glass Phys Chem, 50:3 (2024), 227
M. A. Girsova, G. F. Golovina, I. N. Anfimova, L. N. Kurilenko, T. V. Antropova, “Photoluminophores Based on Porous Glasses Coactivated by Cu2+ and Y3+: Synthesis and Spectral Properties”, Glass Phys Chem, 50:4 (2024), 347
M. A. Girsova, G. F. Golovina, L. N. Kurilenko, I. N. Anfimova, “Spectral Properties of Nanostructured Composite Glass Materials Activated by Yttrium in the Presence of Copper or Bismuth”, Fizika i khimiya stekla, 49:6 (2023), 619
M. I. Yalandin, V. I. Solomonov, A. V. Spirina, S. A. Shunailov, K. A. Sharypov, A. S. Makarova, A. I. Lipchak, “SPECIFIC FEATURES OF PULSED CATHODOLUMINESCENCE UNDER EXCITATION BY NANOSECOND AND SUBNANOSECOND ELECTRON BEAMS”, Doklady Rossiiskoi akademii nauk. Fizika, tekhnicheskie nauki, 508:1 (2023), 19
M. I. Yalandin, V. I. Solomonov, A. V. Spirina, S. A. Shunailov, K. A. Sharypov, A. S. Makarova, A. I. Lipchak, “Specific Features of Pulsed Cathodoluminescence under Excitation by Nanosecond and Subnanosecond Electron Beams”, Dokl. Phys., 68:2 (2023), 50
M. A. Girsova, G. F. Golovina, L. N. Kurilenko, I. N. Anfimova, “Spectral Properties of Nanostructured Composite Glass Materials Activated by Yttrium in the Presence of Copper or Bismuth”, Glass Phys Chem, 49:6 (2023), 625
I. V. Krutikova, K. V. Nefedova, “Scintillation Ceramic Nanoparticles Obtained by Solution Combustion Synthesis”, Bull. Russ. Acad. Sci. Phys., 87:S1 (2023), S82
Yucheng Liu, Kaibo Hu, Xiaowen Zhou, Chuanqi Zhang, Fang Gao, Xuewei Li, Yinhua Wan, “Transformation of YF3 into Y(OH)3 by a Mechanochemical Process: Extracting Yttrium from Rare Earth Smelting Slag under Mild Conditions”, ACS Sustainable Chem. Eng., 11:13 (2023), 4969
V. V. Malyutina-Bronskaya, A. S. Soroka, D. V. Senkevich, M. S. Tarasenko, A. A. Ryadun, N. G. Naumov, “OPTICAL PROPERTIES OF RARE-EARTH ELEMENTS OXOSELENIDES OF OPTICAL PURITY”, Ž. prikl. spektrosk. (Minsk), 89:5 (2022), 626
L. I. Shchepina, R. Yu. Shendrik, E. V. Mezhova, N. A. Ivanov, L. I. Ruzhnikov, “Uranium Photoluminescence Excited in the Charge Transfer Band of Unirradiated LiF–UO2 Crystals”, Bull. Russ. Acad. Sci. Phys., 86:7 (2022), 806
S. V. Zvonarev, V. A. Pankov, V. Yu. Churkin, THE VIII INTERNATIONAL YOUNG RESEARCHERS' CONFERENCE – PHYSICS, TECHNOLOGY, INNOVATIONS (PTI-2021), 2466, THE VIII INTERNATIONAL YOUNG RESEARCHERS' CONFERENCE – PHYSICS, TECHNOLOGY, INNOVATIONS (PTI-2021), 2022, 030016
S. Kononenko, E. Barannik, V. Zhurenko, O. Kalantaryan, V. Chishkala, R. Skiba, S. Lytovchenko, 2022 IEEE 12th International Conference Nanomaterials: Applications & Properties (NAP), 2022, NRA09-1
V. V. Malyutina-Bronskaya, A. S. Soroka, D. V. Senkevich, M. S. Tarasenko, A. A. Ryadun, N. G. Naumov, “Optical Properties of Optically Pure Rare-Earth-Element Oxyselenides”, J Appl Spectrosc, 89:5 (2022), 839
O. Kalantaryan, S. Kononenko, E. Barannik, V. Zhurenko, V. Chishkala, 2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP), 2021, 1
E. Kh. Baksht, M. V. Erofeev, V. F. Tarasenko, M. I. Solomonov, V. A. Shitov, “Yttrium Sesquioxide Ceramics Glow Under Irradiation with an Electron Beam”, Russ Phys J, 63:7 (2020), 1150
O. Kalantaryan, V. Zhurenko, S. Kononenko, R. Skiba, V. Chishkala, M. Azarenkov, 2020 IEEE 10th International Conference Nanomaterials: Applications & Properties (NAP), 2020, 01NP03-1
Citation in format AMSBIB
Contact us: