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Applied optics
About the possibilities of multidimensional equidistant absorption spectroscopy in a broad frequency range in oil thermal distillation fractions research
N. I. Egorovaa, I. O. Konyushenkob, V. M. Nemetsc, S. A. Peganovd a Saint-Petersburg University of State Fire Service of Emercom of Russia
b JSC Research and Production Complex Direction Finder, St. Petersburg, Russia
c Saint Petersburg State University
d JSC Scientific Research Institute of Automation Problems North Computer Complex, St. Petersburg, Russia
Abstract:
The features and possibilities of absorption molecular spectroscopy of complex mixtures of organic compounds by the instance of oil thermal distillation fractions are studied. The problem of studying the spectra of oil fractions as a single object of complex molecular composition was directly solved (i.e. without studing of molecular composition). Thereby multidimensional equidistant spectra were studied in a wide spectral range. Measurement conditions: frequency range from 500 to 1500 cm$^{-1}$, spectral resolution 1 cm$^{-1}$, frequency increment 0.5 cm$^{-1}$, Objects under investigation – 33 fractions of thermal oil distillation. Results processing of spectroscopic measurements was carried out using methods of multifactor mathematical statistics. The efficiency of using absorption molecular spectroscopy in the far infrared region in the study and control of the optical characteristics (absorption spectra) of oil thermal distillation fractions is shown.
Keywords:
absorption molecular spectroscopy, far infrared region, thermal oil distillation fractions, multidimensional equidistant spectra, principal component analysis, spectra of petroleum fractions displayed on the statistical plane and multidimensional space of principal components, informational ability of the spectra.
Received: 13.11.2019 Revised: 24.12.2019 Accepted: 26.12.2019
Citation:
N. I. Egorova, I. O. Konyushenko, V. M. Nemets, S. A. Peganov, “About the possibilities of multidimensional equidistant absorption spectroscopy in a broad frequency range in oil thermal distillation fractions research”, Optics and Spectroscopy, 128:4 (2020), 564–572; Optics and Spectroscopy, 128:4 (2020), 553–561
Linking options:
https://www.mathnet.ru/eng/os441 https://www.mathnet.ru/eng/os/v128/i4/p564
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Abstract page: | 51 | Full-text PDF : | 9 |
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