Optics and Spectroscopy
RUS  ENG    JOURNALS   PEOPLE   ORGANISATIONS   CONFERENCES   SEMINARS   VIDEO LIBRARY   PACKAGE AMSBIB  
General information
Latest issue
Archive

Search papers
Search references

RSS
Latest issue
Current issues
Archive issues
What is RSS



Optics and Spectroscopy:
Year:
Volume:
Issue:
Page:
Find






Personal entry:
Login:
Password:
Save password
Enter
Forgotten password?
Register


Optics and Spectroscopy, 2020, Volume 128, Issue 5, Pages 583–588
DOI: https://doi.org/10.21883/OS.2020.05.49312.348-19
(Mi os410)
 

Spectroscopy and physics of atoms and molecules

Determination of the energy structure and spectroscopic parameters of the vibrational state $(v_{5}=v_{12}=1)$ of the C$_{2}$D$_{4}$ molecule

A. G. Ziatkova, M. A. Merkulova, Yu. V. Konova

Tomsk Polytechnic University
Abstract: Using a Bruker IFS 125HR Fourier spectrometer, the vibrational-rotational structure of the $\nu_{5}+\nu_{12}$ band of the C$_{2}$D$_{4}$ molecule has been detected for the first time with a resolution of 0.0025 cm$^{-1}$. At the initial investigation stage, interpretation of transitions in the spectrum is carried out; at a later stage, results of the interpretation are used as experimental data for solving the inverse spectroscopic problem. The set of 12 spectroscopic parameters of the vibrational state under study is determined for the first time. The root-mean-square deviation amounts to 0.0013 cm$^{-1}$.
Keywords: vibrational–rotational structure, deuterated isotopolog of ethylene, rotational constants, Watson Hamiltonian, $b$-type transitions.
Funding agency Grant number
Russian Foundation for Basic Research 18-02-00819 À
18-32-00116 ìîë_à
The study was supported by the Russian Foundation for Basic Research, project nos. 18-02-00819 A and 18-32-00116 mol_a.
Received: 24.12.2019
Revised: 24.12.2019
Accepted: 27.01.2020
English version:
Optics and Spectroscopy, 2020, Volume 128, Issue 5, Pages 569–574
DOI: https://doi.org/10.1134/S0030400X20050203
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: A. G. Ziatkova, M. A. Merkulova, Yu. V. Konova, “Determination of the energy structure and spectroscopic parameters of the vibrational state $(v_{5}=v_{12}=1)$ of the C$_{2}$D$_{4}$ molecule”, Optics and Spectroscopy, 128:5 (2020), 583–588; Optics and Spectroscopy, 128:5 (2020), 569–574
Citation in format AMSBIB
\Bibitem{ZiaMerKon20}
\by A.~G.~Ziatkova, M.~A.~Merkulova, Yu.~V.~Konova
\paper Determination of the energy structure and spectroscopic parameters of the vibrational state $(v_{5}=v_{12}=1)$ of the C$_{2}$D$_{4}$ molecule
\jour Optics and Spectroscopy
\yr 2020
\vol 128
\issue 5
\pages 583--588
\mathnet{http://mi.mathnet.ru/os410}
\crossref{https://doi.org/10.21883/OS.2020.05.49312.348-19}
\elib{https://elibrary.ru/item.asp?id=43800638}
\transl
\jour Optics and Spectroscopy
\yr 2020
\vol 128
\issue 5
\pages 569--574
\crossref{https://doi.org/10.1134/S0030400X20050203}
Linking options:
  • https://www.mathnet.ru/eng/os410
  • https://www.mathnet.ru/eng/os/v128/i5/p583
  • Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
    Optics and Spectroscopy Optics and Spectroscopy
    Statistics & downloads:
    Abstract page:23
    Full-text PDF :8
     
      Contact us:
     Terms of Use  Registration to the website  Logotypes © Steklov Mathematical Institute RAS, 2024