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Optics and Spectroscopy, 2020, Volume 128, Issue 9, Pages 1231–1237
DOI: https://doi.org/10.21883/OS.2020.09.49857.294-20 (Mi os295) 		 
This article is cited in 5 scientific papers (total in 5 papers)

Spectroscopy and physics of atoms and molecules

Calibration free laser-induced breakdown spectroscopy of zooplankton

N. I. Sushkova, N. V. Lobusb, I. V. Seliverstovaa, T. A. Labutina

a Lomonosov Moscow State University, Faculty of Chemistry
b P. P. Shirshov Institute of Oceanology, Russian Academy of Sciences
Full-text PDF (210 kB) Citations (5)
DOI: https://doi.org/10.21883/OS.2020.09.49857.294-20
Abstract: This study deals with the determination of ratios of light metals (Li, Na, K, Mg, and Ca) in zooplankton (Calanus spp.) by calibration free laser-induced breakdown spectroscopy, assuming local thermodynamic equilibrium. The temperature of laser-induced plasma of zooplankton was derived from rotation-vibration bands of CN, and the electron density was calculated by Stark broadening of Mg I 383.23 nm, Li I 610.37 nm, and Ca II 396.85 nm lines. The synthetic spectra calculated with a radiation transport model for the experimental values of T and Ne were used for a selection of analytical atomic lines free from self-absorption. We compared the obtained data with the results of atomic emission and mass spectrometry with inductively coupled plasma. We also discussed the influence of ionization equilibrium on the accuracy of the results. We propose the presented method for direct semi-quantitative determination of Li, Mg, and Ca ratios in zooplankton.
Keywords: laser-induced breakdown spectroscopy, calibration-free analysis, plasma diagnostics, light metals, ionization, zooplankton.
Funding agency Grant number
Russian Foundation for Basic Research 18-33-01297
Russian Science Foundation 18-77-00064
The study was supported by the Russian Foundation for Basic Research (project no. 18-33-01297). Analyzes of zooplankton by ICP-AES and ICP-MS and analyzes of organic carbon and ash were supported by the Russian Science Foundation (project no. 18-77-00064).
Received: 20.10.2019
Revised: 07.02.2020
Accepted: 29.05.2020
English version:
Optics and Spectroscopy, 2020, Volume 128, Issue 9, Pages 1343–1349
DOI: https://doi.org/10.1134/S0030400X20090222
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: N. I. Sushkov, N. V. Lobus, I. V. Seliverstova, T. A. Labutin, “Calibration free laser-induced breakdown spectroscopy of zooplankton”, Optics and Spectroscopy, 128:9 (2020), 1231–1237; Optics and Spectroscopy, 128:9 (2020), 1343–1349
Citation in format AMSBIB
\Bibitem{SusLobSel20}
\by N.~I.~Sushkov, N.~V.~Lobus, I.~V.~Seliverstova, T.~A.~Labutin
\paper Calibration free laser-induced breakdown spectroscopy of zooplankton
\jour Optics and Spectroscopy
\yr 2020
\vol 128
\issue 9
\pages 1231--1237
\mathnet{http://mi.mathnet.ru/os295}
\crossref{https://doi.org/10.21883/OS.2020.09.49857.294-20}
\elib{https://elibrary.ru/item.asp?id=44154080}
\transl
\jour Optics and Spectroscopy
\yr 2020
\vol 128
\issue 9
\pages 1343--1349
\crossref{https://doi.org/10.1134/S0030400X20090222}
Linking options:
  • https://www.mathnet.ru/eng/os295
  • https://www.mathnet.ru/eng/os/v128/i9/p1231
    • This publication is cited in the following 5 articles:
    1. Nikolai I. Sushkov, Timur A. Labutin, “Laser-induced breakdown spectroscopy of biological tissues: Plasma diagnostics and a comparison of quantification approaches”, Spectrochimica Acta Part B: Atomic Spectroscopy, 211 (2024), 106834  crossref
    2. N. I. Sushkov, N. N. Kurian, S. N. Anuchin, S. M. Zaytsev, “Combined Use of Laser-Induced Breakdown and X-Ray Fluorescence Spectroscopies for Elemental Analysis of Aquatic Organisms”, J Appl Spectrosc, 90:6 (2024), 1273  crossref
    3. Dennis Silva Ferreira, Diego Victor Babos, Mauro Henrique Lima-Filho, Heloisa Froehlick Castello, Alejandro C. Olivieri, Fabiola Manhas Verbi Pereira, Edenir Rodrigues Pereira-Filho, “Laser-induced breakdown spectroscopy (LIBS): calibration challenges, combination with other techniques, and spectral analysis using data science”, J. Anal. At. Spectrom., 2024  crossref
    4. Nikolai I. Sushkov, Gábor Galbács, Krisztián Fintor, Nikolay V. Lobus, Timur A. Labutin, “A novel approach for discovering correlations between elemental and molecular composition using laser-based spectroscopic techniques”, Analyst, 147:14 (2022), 3248  crossref
    5. Siyu Zhang, Zhenlin Hu, Zhifang Zhao, Feng Chen, Yun Tang, Ziqian Sheng, Deng Zhang, Zhanjie Zhang, Honglin Jin, Huangsheng Pu, Lianbo Guo, “Quantitative analysis of mineral elements in hair and nails using calibration-free laser-induced breakdown spectroscopy”, Optik, 242 (2021), 167067  crossref
    Citing articles in Google Scholar: Russian citations, English citations
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