Abstract:
The luminescence spectra of coal fractions with dimensions d⩽ 63 μm were studied directly during the action of neodymium laser pulses (τi = 120 μs). Depending on the radiation energy density H, the luminescence spectra have a different character. The glow at minimum values of the laser pulse energy density H(1)cr is associated with the ignition of fine coal particulates (∼1 μm) present in the fractions, and with the ignition of reactive microprotrusions on the surface of larger coal particles. The luminescence spectra at this stage are of a non-thermal nature and are associated with the radiation of volatile molecules in the gas phase and their oxidation products. With an increase in the laser pulse energy density H, a thermal glow of the surface of larger coal particles is observed, which is described by the Planck formula at T = 3100 K. When H=H(2)cr is reached, the surface of the coal particles ignites during the action of the laser pulse. Contributions to the spectra are the glow of the surface of coal particles, emitted carbon particles, and the glow associated with the emission of excited molecules H2, H2O, CO2. With an increase in H>H(2)cr, the processes leading to the glow of coal particles during a laser pulse are similar to those described above for H(2)cr, but the glow intensity increases.
The work was financially supported by the Russian Foundation for Basic Research (project no. 20-43-420019р_а) and was carried out within the framework of the State Assignments of the Institute of Coal Chemistry and Material Science of Siberian Branch of the Russian Academy of Sciences, of Federal Research Center of Coal and Coal Chemistry of Siberian Branch of the Russian Academy of Sciences (project AAAA-A17-117041910150-2, head B.P. Aduev) on the equipment of the Center for Collective Use of the Federal Research Center of Coal and Coal Chemistry of Siberian Branch of the Russian Academy of Sciences.
Citation:
B. P. Aduev, D. R. Nurmuhametov, Ya. V. Kraft, Z. R. Ismagilov, “Glow spectral characteristics of the hard coal particles surface during the action of laser pulses in the free generation mode”, Optics and Spectroscopy, 128:12 (2020), 1898–1904; Optics and Spectroscopy, 128:12 (2020), 2008–2014
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\paper Glow spectral characteristics of the hard coal particles surface during the action of laser pulses in the free generation mode
\jour Optics and Spectroscopy
\yr 2020
\vol 128
\issue 12
\pages 1898--1904
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\crossref{https://doi.org/10.21883/OS.2020.12.50327.187-20}
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\jour Optics and Spectroscopy
\yr 2020
\vol 128
\issue 12
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\crossref{https://doi.org/10.1134/S0030400X20120838}
Linking options:
https://www.mathnet.ru/eng/os231
https://www.mathnet.ru/eng/os/v128/i12/p1898
This publication is cited in the following 12 articles:
B. P. Aduev, Y. V. Kraft, D. R. Nurmukhametov, Z. R. Ismagilov, “A study on the ignition of different metamorphic grade coal particles by microsecond laser pulses in the free-running mode”, Combustion Science and Technology, 196:2 (2024), 274
B. P. Aduev, D. R. Nurmukhametov, Ya. V. Kraft, Z. R. Ismagilov, “Ignition of Coal Microparticles by Laser Pulses of the Second Harmonic of a Neodymium Laser in the Q-Switched Regime”, Russ. J. Phys. Chem. B, 18:2 (2024), 468
B. P. Aduev, D. R. Nurmukhametov, Ya. V. Kraft, Z. R. Ismagilov, “Ignition of Coal Microparticles by Laser Pulses of The Second Harmonic of a Ndodymium Laser in the Q-Switched Regime”, Himičeskaâ fizika, 43:3 (2024), 55
B. P. Aduev, G. M. Belokurov, I. Yu. Liskov, Z. R. Ismagilov, “Ignition of Coals with Continuous-Wave Lasers at Wavelengths of 450 and 808 nm”, Khimiya tverdogo topliva, 2023, no. 4, 31
Ya. V. Kraft, B. P. Aduev, N. V. Nelubina, V. D. Volkov, Z. R. Ismagilov, “Pyrolysis of Coal by Nanosecond Laser Pulses”, Coke Chem., 66:9 (2023), 449
Ya. V. Kraft, B. P. Aduev, V. D. Volkov, Z. R. Ismagilov, “Mass spectrometric study of composition of gaseous products of coal laser pyrolysis”, Combustion, Explosion and Shock Waves, 59:3 (2023), 334–343
B. P. Aduev, G. M. Belokurov, I. Yu. Liskov, Z. R. Ismagilov, “Ignition of Coals with Continuous-Wave Lasers at Wavelengths of 450 and 808 nm”, Solid Fuel Chem., 57:3 (2023), 170
Ya. V. Kraft, O. M. Gavrilyuk, Z. R. Ismagilov, “Low-Temperature Pyrolysis of Kuznetsk Basin Coal: Composition of the Products”, Coke Chem., 66:1 (2023), 17
B. P. Aduev, D. R. Nurmuhametov, Ya. V. Kraft, Z. R. Ismagilov, “Pulsed laser ignition of coal microparticles”, Combustion, Explosion and Shock Waves, 58:5 (2022), 610–619
B.P. Aduev, G.M. Belokurov, I.Yu. Liskov, D.R. Nurmukhametov, Z.R. Ismagilov, “Ignition of Low-Metamorphized Coal with Continuous Lasers at Wavelengths 450 nm and 808 nm”, Eurasian Chem. Tech. J., 24:2 (2022), 91
Ya. V. Kraft, B. P. Aduev, T. V. Dikunova, Z. R. Ismagilov, “Composition of Coal Tar from the Laser Pyrolysis of Coal”, Coke Chem., 65:9 (2022), 392
B. P. Aduev, D. R. Nurmukhametov, Ya. V. Kraft, Z. R. Ismagilov, “Initial Stages of The Ignition of Coal Microparticles of Different Grades by Laser Pulses”, Russ. J. Phys. Chem. B, 16:2 (2022), 227