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Optics and Spectroscopy, 2020, Volume 128, Issue 12, Pages 1898–1904
DOI: https://doi.org/10.21883/OS.2020.12.50327.187-20
(Mi os231)
 

This article is cited in 12 scientific papers (total in 12 papers)

Laser physics and laser optics

Glow spectral characteristics of the hard coal particles surface during the action of laser pulses in the free generation mode

B. P. Aduev, D. R. Nurmuhametov, Ya. V. Kraft, Z. R. Ismagilov

The Federal Research Center of Coal and Coal Chemistry of Siberian Branch of the Russian Academy of Sciences, Kemerovo, Russia
Abstract: The luminescence spectra of coal fractions with dimensions $d\le$ 63 $\mu$m were studied directly during the action of neodymium laser pulses ($\tau_i$ = 120 $\mu$s). Depending on the radiation energy density $H$, the luminescence spectra have a different character. The glow at minimum values of the laser pulse energy density $H_{cr}^{(1)}$ is associated with the ignition of fine coal particulates ($\sim$1 $\mu$m) present in the fractions, and with the ignition of reactive microprotrusions on the surface of larger coal particles. The luminescence spectra at this stage are of a non-thermal nature and are associated with the radiation of volatile molecules in the gas phase and their oxidation products. With an increase in the laser pulse energy density $H$, a thermal glow of the surface of larger coal particles is observed, which is described by the Planck formula at $T$ = 3100 K. When $H=H_{cr}^{(2)}$ is reached, the surface of the coal particles ignites during the action of the laser pulse. Contributions to the spectra are the glow of the surface of coal particles, emitted carbon particles, and the glow associated with the emission of excited molecules H$_{2}$, H$_{2}$O, CO$_{2}$. With an increase in $H>H_{cr}^{(2)}$, the processes leading to the glow of coal particles during a laser pulse are similar to those described above for $H_{cr}^{(2)}$, but the glow intensity increases.
Keywords: coal, laser, ignition, volatile substances, degree of coalification, coke residue.
Funding agency Grant number
Ministry of Science and Higher Education of the Russian Federation АААА-А17-117041910150-2
Russian Foundation for Basic Research 20-43-420019 р_а
The work was financially supported by the Russian Foundation for Basic Research (project no. 20-43-420019р_а) and was carried out within the framework of the State Assignments of the Institute of Coal Chemistry and Material Science of Siberian Branch of the Russian Academy of Sciences, of Federal Research Center of Coal and Coal Chemistry of Siberian Branch of the Russian Academy of Sciences (project AAAA-A17-117041910150-2, head B.P. Aduev) on the equipment of the Center for Collective Use of the Federal Research Center of Coal and Coal Chemistry of Siberian Branch of the Russian Academy of Sciences.
Received: 02.07.2020
Revised: 02.07.2020
Accepted: 10.08.2020
English version:
Optics and Spectroscopy, 2020, Volume 128, Issue 12, Pages 2008–2014
DOI: https://doi.org/10.1134/S0030400X20120838
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: B. P. Aduev, D. R. Nurmuhametov, Ya. V. Kraft, Z. R. Ismagilov, “Glow spectral characteristics of the hard coal particles surface during the action of laser pulses in the free generation mode”, Optics and Spectroscopy, 128:12 (2020), 1898–1904; Optics and Spectroscopy, 128:12 (2020), 2008–2014
Citation in format AMSBIB
\Bibitem{AduNurKra20}
\by B.~P.~Aduev, D.~R.~Nurmuhametov, Ya.~V.~Kraft, Z.~R.~Ismagilov
\paper Glow spectral characteristics of the hard coal particles surface during the action of laser pulses in the free generation mode
\jour Optics and Spectroscopy
\yr 2020
\vol 128
\issue 12
\pages 1898--1904
\mathnet{http://mi.mathnet.ru/os231}
\crossref{https://doi.org/10.21883/OS.2020.12.50327.187-20}
\elib{https://elibrary.ru/item.asp?id=44866917}
\transl
\jour Optics and Spectroscopy
\yr 2020
\vol 128
\issue 12
\pages 2008--2014
\crossref{https://doi.org/10.1134/S0030400X20120838}
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  • This publication is cited in the following 12 articles:
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
    Optics and Spectroscopy Optics and Spectroscopy
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