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Optics and Spectroscopy, 2020, Volume 128, Issue 12, Pages 1898–1904
DOI: https://doi.org/10.21883/OS.2020.12.50327.187-20
(Mi os231)
 

This article is cited in 12 scientific papers (total in 12 papers)

Laser physics and laser optics

Glow spectral characteristics of the hard coal particles surface during the action of laser pulses in the free generation mode

B. P. Aduev, D. R. Nurmuhametov, Ya. V. Kraft, Z. R. Ismagilov

The Federal Research Center of Coal and Coal Chemistry of Siberian Branch of the Russian Academy of Sciences, Kemerovo, Russia
Abstract: The luminescence spectra of coal fractions with dimensions d 63 μm were studied directly during the action of neodymium laser pulses (τi = 120 μs). Depending on the radiation energy density H, the luminescence spectra have a different character. The glow at minimum values of the laser pulse energy density H(1)cr is associated with the ignition of fine coal particulates (1 μm) present in the fractions, and with the ignition of reactive microprotrusions on the surface of larger coal particles. The luminescence spectra at this stage are of a non-thermal nature and are associated with the radiation of volatile molecules in the gas phase and their oxidation products. With an increase in the laser pulse energy density H, a thermal glow of the surface of larger coal particles is observed, which is described by the Planck formula at T = 3100 K. When H=H(2)cr is reached, the surface of the coal particles ignites during the action of the laser pulse. Contributions to the spectra are the glow of the surface of coal particles, emitted carbon particles, and the glow associated with the emission of excited molecules H2, H2O, CO2. With an increase in H>H(2)cr, the processes leading to the glow of coal particles during a laser pulse are similar to those described above for H(2)cr, but the glow intensity increases.
Keywords: coal, laser, ignition, volatile substances, degree of coalification, coke residue.
Funding agency Grant number
Ministry of Science and Higher Education of the Russian Federation АААА-А17-117041910150-2
Russian Foundation for Basic Research 20-43-420019 р_а
The work was financially supported by the Russian Foundation for Basic Research (project no. 20-43-420019р_а) and was carried out within the framework of the State Assignments of the Institute of Coal Chemistry and Material Science of Siberian Branch of the Russian Academy of Sciences, of Federal Research Center of Coal and Coal Chemistry of Siberian Branch of the Russian Academy of Sciences (project AAAA-A17-117041910150-2, head B.P. Aduev) on the equipment of the Center for Collective Use of the Federal Research Center of Coal and Coal Chemistry of Siberian Branch of the Russian Academy of Sciences.
Received: 02.07.2020
Revised: 02.07.2020
Accepted: 10.08.2020
English version:
Optics and Spectroscopy, 2020, Volume 128, Issue 12, Pages 2008–2014
DOI: https://doi.org/10.1134/S0030400X20120838
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: B. P. Aduev, D. R. Nurmuhametov, Ya. V. Kraft, Z. R. Ismagilov, “Glow spectral characteristics of the hard coal particles surface during the action of laser pulses in the free generation mode”, Optics and Spectroscopy, 128:12 (2020), 1898–1904; Optics and Spectroscopy, 128:12 (2020), 2008–2014
Citation in format AMSBIB
\Bibitem{AduNurKra20}
\by B.~P.~Aduev, D.~R.~Nurmuhametov, Ya.~V.~Kraft, Z.~R.~Ismagilov
\paper Glow spectral characteristics of the hard coal particles surface during the action of laser pulses in the free generation mode
\jour Optics and Spectroscopy
\yr 2020
\vol 128
\issue 12
\pages 1898--1904
\mathnet{http://mi.mathnet.ru/os231}
\crossref{https://doi.org/10.21883/OS.2020.12.50327.187-20}
\elib{https://elibrary.ru/item.asp?id=44866917}
\transl
\jour Optics and Spectroscopy
\yr 2020
\vol 128
\issue 12
\pages 2008--2014
\crossref{https://doi.org/10.1134/S0030400X20120838}
Linking options:
  • https://www.mathnet.ru/eng/os231
  • https://www.mathnet.ru/eng/os/v128/i12/p1898
  • This publication is cited in the following 12 articles:
    1. B. P. Aduev, Y. V. Kraft, D. R. Nurmukhametov, Z. R. Ismagilov, “A study on the ignition of different metamorphic grade coal particles by microsecond laser pulses in the free-running mode”, Combustion Science and Technology, 196:2 (2024), 274  crossref
    2. B. P. Aduev, D. R. Nurmukhametov, Ya. V. Kraft, Z. R. Ismagilov, “Ignition of Coal Microparticles by Laser Pulses of the Second Harmonic of a Neodymium Laser in the Q-Switched Regime”, Russ. J. Phys. Chem. B, 18:2 (2024), 468  crossref
    3. B. P. Aduev, D. R. Nurmukhametov, Ya. V. Kraft, Z. R. Ismagilov, “Ignition of Coal Microparticles by Laser Pulses of The Second Harmonic of a Ndodymium Laser in the Q-Switched Regime”, Himičeskaâ fizika, 43:3 (2024), 55  crossref
    4. B. P. Aduev, G. M. Belokurov, I. Yu. Liskov, Z. R. Ismagilov, “Ignition of Coals with Continuous-Wave Lasers at Wavelengths of 450 and 808 nm”, Khimiya tverdogo topliva, 2023, no. 4, 31  crossref
    5. Ya. V. Kraft, B. P. Aduev, N. V. Nelubina, V. D. Volkov, Z. R. Ismagilov, “Pyrolysis of Coal by Nanosecond Laser Pulses”, Coke Chem., 66:9 (2023), 449  crossref
    6. Ya. V. Kraft, B. P. Aduev, V. D. Volkov, Z. R. Ismagilov, “Mass spectrometric study of composition of gaseous products of coal laser pyrolysis”, Combustion, Explosion and Shock Waves, 59:3 (2023), 334–343  mathnet  mathnet  crossref  crossref
    7. B. P. Aduev, G. M. Belokurov, I. Yu. Liskov, Z. R. Ismagilov, “Ignition of Coals with Continuous-Wave Lasers at Wavelengths of 450 and 808 nm”, Solid Fuel Chem., 57:3 (2023), 170  crossref
    8. Ya. V. Kraft, O. M. Gavrilyuk, Z. R. Ismagilov, “Low-Temperature Pyrolysis of Kuznetsk Basin Coal: Composition of the Products”, Coke Chem., 66:1 (2023), 17  crossref
    9. B. P. Aduev, D. R. Nurmuhametov, Ya. V. Kraft, Z. R. Ismagilov, “Pulsed laser ignition of coal microparticles”, Combustion, Explosion and Shock Waves, 58:5 (2022), 610–619  mathnet  mathnet  crossref  crossref
    10. B.P. Aduev, G.M. Belokurov, I.Yu. Liskov, D.R. Nurmukhametov, Z.R. Ismagilov, “Ignition of Low-Metamorphized Coal with Continuous Lasers at Wavelengths 450 nm and 808 nm”, Eurasian Chem. Tech. J., 24:2 (2022), 91  crossref
    11. Ya. V. Kraft, B. P. Aduev, T. V. Dikunova, Z. R. Ismagilov, “Composition of Coal Tar from the Laser Pyrolysis of Coal”, Coke Chem., 65:9 (2022), 392  crossref
    12. B. P. Aduev, D. R. Nurmukhametov, Ya. V. Kraft, Z. R. Ismagilov, “Initial Stages of The Ignition of Coal Microparticles of Different Grades by Laser Pulses”, Russ. J. Phys. Chem. B, 16:2 (2022), 227  crossref
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