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This article is cited in 2 scientific papers (total in 2 papers)
Spectroscopy and physics of atoms and molecules
Dipole-dipole polarizability of the cadmium $^1$S$_0$ state revisited
Uwe Hohm Technische Universität Braunschweig, Institut fur Physikalische und Theoretische Chemie, Braunschweig, Germany
Abstract:
Experimental results and high-level quantum chemical ab initio calculations of the static polarizability $\alpha = \alpha(\omega = 0)$ of the cadmium $^1$S$_0$ state are still in marked disagreement. Here we analyze this discrepancy by using experimentally determined dipole oscillator strength distributions (DOSD). It will be shown that within this procedure the experimentally determined static polarizability $\alpha_0$ will shift from 49.7 $\pm$ 1.6 au to considerably lower values. We now conclude an experimentally determined polarizability of $\alpha_0$ = 47.5 $\pm$ 2.0 au in much better agreement with the latest calculations of $\alpha_0\approx$ 46 au.
Keywords:
cadmium, polarizability, DOSD.
Received: 23.06.2021 Revised: 03.08.2021 Accepted: 03.08.2021
Citation:
Uwe Hohm, “Dipole-dipole polarizability of the cadmium $^1$S$_0$ state revisited”, Optics and Spectroscopy, 129:12 (2021), 1483; Optics and Spectroscopy, 130:4 (2022), 290–294
Linking options:
https://www.mathnet.ru/eng/os1119 https://www.mathnet.ru/eng/os/v129/i12/p1483
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