Abstract:
Experimental results and high-level quantum chemical ab initio calculations of the static polarizability α=α(ω=0) of the cadmium 1S0 state are still in marked disagreement. Here we analyze this discrepancy by using experimentally determined dipole oscillator strength distributions (DOSD). It will be shown that within this procedure the experimentally determined static polarizability α0 will shift from 49.7 ± 1.6 au to considerably lower values. We now conclude an experimentally determined polarizability of α0 = 47.5 ± 2.0 au in much better agreement with the latest calculations of α0≈ 46 au.
Citation:
Uwe Hohm, “Dipole-dipole polarizability of the cadmium 1S0 state revisited”, Optics and Spectroscopy, 129:12 (2021), 1483; Optics and Spectroscopy, 130:4 (2022), 290–294
\Bibitem{Hoh21}
\by Uwe~Hohm
\paper Dipole-dipole polarizability of the cadmium $^1$S$_0$ state revisited
\jour Optics and Spectroscopy
\yr 2021
\vol 129
\issue 12
\pages 1483
\mathnet{http://mi.mathnet.ru/os1119}
\transl
\jour Optics and Spectroscopy
\yr 2022
\vol 130
\issue 4
\pages 290--294
\crossref{https://doi.org/10.1134/S0030400X22040105}
Linking options:
https://www.mathnet.ru/eng/os1119
https://www.mathnet.ru/eng/os/v129/i12/p1483
This publication is cited in the following 4 articles:
YingXing Cheng, “Relativistic and electron-correlation effects in static dipole polarizabilities for group 12 elements”, Phys. Chem. Chem. Phys., 2025
Sudipta Chakraborty, Tamoghna Mukhopadhyay, Achintya Kumar Dutta, “Spin-Free Exact Two-Component Linear Response Coupled Cluster Theory for the Estimation of Frequency-Dependent Second-Order Properties”, J. Phys. Chem. A, 2025
Ru-Kui Zhang, Jun Jiang, Chen-Zhong Dong, Yong-Bo Tang, “Dynamic polarizabilities and triply magic trapping conditions for
5s2S01→5s5p3P0,2
transitions of Cd atoms”, Phys. Rev. A, 109:3 (2024)
Xiang Yuan, Loïc Halbert, Johann Valentin Pototschnig, Anastasios Papadopoulos, Sonia Coriani, Lucas Visscher, André Severo Pereira Gomes, “Formulation and Implementation of Frequency-Dependent Linear Response Properties with Relativistic Coupled Cluster Theory for GPU-Accelerated Computer Architectures”, J. Chem. Theory Comput., 20:2 (2024), 677