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Optics and Spectroscopy, 2018, Volume 124, Issue 1, Pages 45–50
DOI: https://doi.org/10.21883/OS.2018.01.45355.113-17
(Mi os1089)
 

This article is cited in 1 scientific paper (total in 1 paper)

Spectroscopy of condensed matter

Peculiarities of the sers spectra of 4,4'-bipyridine molecule in a single molecule detection regime

A. M. Polubotkoa, E. V. Solovyevab

a A.F. Ioffe Physico-Technical Institute, St. Petersburg, 194021, Russia
b Institute of Chemistry, Saint Petersburg State University, Peterhof, St. Petersburg, 198504, Russia
Citations (1)
Abstract: The paper describes briefly main statements of the theory of the SERS spectra with regards to the single molecule regime, when the enhancement achieves the values $\sim$10$^{14}$–10$^{15}$. Analysis of the spectra of 4,4'-bypyridine, obtained on the dimer lattice of sharp nanoparticles points out that the observed enhancement is caused exclusively by a strong quadrupole light-molecule interaction, which manifests in the presence of lines, caused by vibrations with the unit irreducible representations of the $D_2$ and $D_{2h}$ symmetry groups, which apparently describe the symmetry properties of the molecule. The study of the spectra, obtained by tip enhanced spectroscopy demonstrates that the strong quadrupole light-molecule interaction still has a governing role, however the strong dipole interaction still manifests in the existence of very weak forbidden lines. This result apparently is associated with another experimental geometry.
Received: 11.05.2017
English version:
Optics and Spectroscopy, 2018, Volume 124, Issue 1, Pages 43–48
DOI: https://doi.org/10.1134/S0030400X18010162
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: A. M. Polubotko, E. V. Solovyeva, “Peculiarities of the sers spectra of 4,4'-bipyridine molecule in a single molecule detection regime”, Optics and Spectroscopy, 124:1 (2018), 45–50; Optics and Spectroscopy, 124:1 (2018), 43–48
Citation in format AMSBIB
\Bibitem{PolSol18}
\by A.~M.~Polubotko, E.~V.~Solovyeva
\paper Peculiarities of the sers spectra of 4,4'-bipyridine molecule in a single molecule detection regime
\jour Optics and Spectroscopy
\yr 2018
\vol 124
\issue 1
\pages 45--50
\mathnet{http://mi.mathnet.ru/os1089}
\crossref{https://doi.org/10.21883/OS.2018.01.45355.113-17}
\elib{https://elibrary.ru/item.asp?id=32740080}
\transl
\jour Optics and Spectroscopy
\yr 2018
\vol 124
\issue 1
\pages 43--48
\crossref{https://doi.org/10.1134/S0030400X18010162}
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  • https://www.mathnet.ru/eng/os/v124/i1/p45
  • This publication is cited in the following 1 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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