Abstract:
The results of measurements of the scattering matrix at a wavelength of 0.63 μμm in the range of scattering angles of 10∘∘–155∘∘ are presented for an aqueous suspension of lead oxide containing particles of plate form and their aggregates of monomers with dimensions of ∼∼5 nm. The results of the measurements are compared with the results of calculations for axially symmetric scatterers (ellipsoids of rotation, cylinders). It is shown that the presence of aggregates affects the scattering properties of such a medium. The results of reconstructing the distribution of particles of a disperse medium in sizes from the measurements data of the scattering matrix are presented. The reconstruction of the distributions was carried out by solving the problem of optimizing the sum of the squared deviations of the experimental and calculated values of matrix elements in the framework of the model of axially symmetric scatterers. It is shown that the distribution of particles by sizes is more accurately reconstructed by minimizing the sum of the squares of the deviations for the sum of the diagonal elements. The obtained distribution is compared with the distribution measured by the method of dynamic light scattering.
Citation:
S. N. Chirikov, A. V. Shkirin, “Determination of the disperse composition of a PbO suspension containing aggregates of particles of lamellar shape by the laser-polarimetry method”, Optics and Spectroscopy, 124:4 (2018), 542–550; Optics and Spectroscopy, 124:4 (2018), 575–584
\Bibitem{ChiShk18}
\by S.~N.~Chirikov, A.~V.~Shkirin
\paper Determination of the disperse composition of a PbO suspension containing aggregates of particles of lamellar shape by the laser-polarimetry method
\jour Optics and Spectroscopy
\yr 2018
\vol 124
\issue 4
\pages 542--550
\mathnet{http://mi.mathnet.ru/os1036}
\crossref{https://doi.org/10.21883/OS.2018.04.45757.267-17}
\elib{https://elibrary.ru/item.asp?id=32740158}
\transl
\jour Optics and Spectroscopy
\yr 2018
\vol 124
\issue 4
\pages 575--584
\crossref{https://doi.org/10.1134/S0030400X18040057}
Linking options:
https://www.mathnet.ru/eng/os1036
https://www.mathnet.ru/eng/os/v124/i4/p542
This publication is cited in the following 6 articles:
A. V. Shkirin, D. N. Ignatenko, S. N. Chirikov, A. V. Vorobev, S. V. Gudkov, “Application of Laser Polarimetric Scatterometry in the Study of Water-Based Multicomponent Bioorganic Systems on the Example of Cow Milk”, Phys. Wave Phen., 30:3 (2022), 186
Vladimir V. Kirsanov, Alexey V. Shkirin, Dmitriy Yu. Pavkin, Dmitry N. Ignatenko, Georgy L. Danielyan, Artyom R. Khakimov, Nikolai F. Bunkin, “Laser Fluorescence and Extinction Methods for Measuring the Flow and Composition of Milk in a Milking Machine”, Photonics, 8:9 (2021), 390
Alexey V. Shkirin, Dmitry N. Ignatenko, Sergey N. Chirikov, Nikolai F. Bunkin, Maxim E. Astashev, Sergey V. Gudkov, “Analysis of Fat and Protein Content in Milk Using Laser Polarimetric Scatterometry”, Agriculture, 11:11 (2021), 1028
M. N. Kirichenko, L. L. Chaikov, A. V. Shkirin, V. I. Krasovskii, N. A. Bulychev, M. A. Kazaryan, S. V. Krivokhizha, F. O. Milovich, S. N. Chirikov, “General Features of Size Distributions and Internal Structure of Particles in Aqueous Nanosuspensions”, Phys. Wave Phen., 28:2 (2020), 140
Nikolai F. Bunkin, Alexey P. Glinushkin, Alexey V. Shkirin, Dmitriy N. Ignatenko, Sergey N. Chirikov, Ivan V. Savchenko, Valery P. Meshalkin, Gennady N. Samarin, Alireza Maleki, Valery P. Kalinitchenko, “Identification of Organic Matter Dispersions Based on Light Scattering Matrices Focusing on Soil Organic Matter Management”, ACS Omega, 5:51 (2020), 33214
Michael I. Mishchenko, “Comprehensive thematic T-matrix reference database: a 2017–2019 update”, Journal of Quantitative Spectroscopy and Radiative Transfer, 242 (2020), 106692