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Nanosystems: Physics, Chemistry, Mathematics, 2020, Volume 11, Issue 5, Pages 529–536
DOI: https://doi.org/10.17586/2220-8054-2020-11-5-529-536 (Mi nano554) 		 
This article is cited in 1 scientific paper (total in 1 paper)

CHEMISTRY AND MATERIAL SCIENCE

A facile low-temperature deposition of Sn-rich tin (II) monosulfide colloid particles

N. S. Kozhevnikovaa, L. N. Maskaevabc, E. E. Lekomtsevab, L. A. Pasechnika, A. Yu. Chufarova, O. A. Lipinaa, A. N. Enyashina, V. F. Markovbc

a Institute of Solid State Chemistry of Ural Branch of the Russian Academy of Sciences, Pervomayskaya, 91, Ekaterinburg, 620990, Russia
b Ural Federal University named B. N. Yeltsin, Mira, 9, Ekaterinburg, 620002, Russia
c Ural Institute of State Fire Service of EMERCOM of Russia, Mira str. 22, 620062, Ekaterinburg
Full-text PDF (1673 kB) Citations (1)
DOI: https://doi.org/10.17586/2220-8054-2020-11-5-529-536
Abstract: A novel, eco-friendly and low temperature synthesis of tin (II) monosulfide colloid particles is described. Chemical bath deposition was successfully applied for the deposition of polynanocrystalline SnS from acidic aqueous solutions. The characterization of the prepared samples was accomplished through elemental analysis, scanning electron microscopy, X-ray powder diffraction, and optical spectroscopy. The composition of tin (II) monosulfide colloids assembled of nanoparticles was found to be Sn-rich. Several simple scenarios for Sn surplus within SnS lattice (S-vacancies at S-sublattice, Sn-atoms intercalated between SnS layers and Sn-doping of S-sites) have been analyzed by means of quantum chemical calculations. The potential application of the Sn$_{1+ x}$ S colloid particles in solar cells as absorber material and as photocatalyst was demonstrated by measuring the optical properties.
Keywords: tin (II) sulfide, chemical bath deposition, optical band gap, Sn-rich.
Funding agency Grant number
Ministry of Science and Higher Education of the Russian Federation AAAA-A19-119031890025-9
Ministry of Education and Science of the Russian Federation 02.A03.21.0006
This work was performed in accordance with the scientific and research plans and state assignment of the ISSC UB RAS (theme AAAA-A19-119031890025-9) and by the Government of the Russian Federation (program 211, project No 02.A03.21.0006).
Received: 18.09.2020
Bibliographic databases:
Document Type: Article
Language: English
Citation: N. S. Kozhevnikova, L. N. Maskaeva, E. E. Lekomtseva, L. A. Pasechnik, A. Yu. Chufarov, O. A. Lipina, A. N. Enyashin, V. F. Markov, “A facile low-temperature deposition of Sn-rich tin (II) monosulfide colloid particles”, Nanosystems: Physics, Chemistry, Mathematics, 11:5 (2020), 529–536
Citation in format AMSBIB
\Bibitem{KozMasLek20}
\by N.~S.~Kozhevnikova, L.~N.~Maskaeva, E.~E.~Lekomtseva, L.~A.~Pasechnik, A.~Yu.~Chufarov, O.~A.~Lipina, A.~N.~Enyashin, V.~F.~Markov
\paper A facile low-temperature deposition of Sn-rich tin (II) monosulfide colloid particles
\jour Nanosystems: Physics, Chemistry, Mathematics
\yr 2020
\vol 11
\issue 5
\pages 529--536
\mathnet{http://mi.mathnet.ru/nano554}
\crossref{https://doi.org/10.17586/2220-8054-2020-11-5-529-536}
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\elib{https://elibrary.ru/item.asp?id=46750794}
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