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This article is cited in 2 scientific papers (total in 2 papers)
CHEMISTRY AND MATERIAL SCIENCE
Microwave synthesis and studies room temperature optical properties of LaF$_3$: Ce$^{3+}$, Pr$^{3+}$, Nd$^{3+}$ nanocrystals
Sidheshwar G Gaurkhede Department of Physics, Bhavan's College of Science, Andheri (W) Mumbai – 400058, India
Abstract:
Lanthanum fluoride (LaF$_{3}$: Ce$^{3+}$, Pr$^{3+}$, Nd$^{3+}$) was synthesized by water soluble LaCl$_{3}$ + CeCl$_{3}$+ PrCl$_{3}$ + NdCl$_{3}$ and NH$_{4}$F as starting materials in de-ionized water as solvent using microwave assisted technique. The structure of LaF$_{3}$: Ce$^{3+}$, Pr$^{3+}$, Nd$^{3+}$ nanocrystals analyzed by XRD and TEM analysis is found to be in hexagonal structure and average crystalline particle size is $20$ nm (JCPDS standard card (32-0483) of pure hexagonal LaF$_3$ crystals). The absorption edge in UV spectra is found at $250$ nm corresponding to energy of $4.9$ eV. It further shows a wide transparent window lying between $200$ nm–$800$ nm. For LaF$_{3}$: Ce$^{3+}$, Pr$^{3+}$, Nd$^{3+}$ nanocrystals emission of blue color ($458$ nm) has been observed with at an excitation wavelength of $254$ nm. The measured relative second harmonic generation (SHG) efficiency of LaF$_{3}$: Ce$^{3+}$, Pr$^{3+}$, Nd$^{3+}$ in de-ionized water with respect to KDP crystal is $0.186$.
Keywords:
microwave radiation, hexagonal shape, x-ray diffraction, luminescent, sHG.
Received: 23.01.2020
Citation:
Sidheshwar G Gaurkhede, “Microwave synthesis and studies room temperature optical properties of LaF$_3$: Ce$^{3+}$, Pr$^{3+}$, Nd$^{3+}$ nanocrystals”, Nanosystems: Physics, Chemistry, Mathematics, 11:1 (2020), 117–122
Linking options:
https://www.mathnet.ru/eng/nano505 https://www.mathnet.ru/eng/nano/v11/i1/p117
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